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New Tridentate Carbamoylmethylphosphine Oxides: Synthesis and NMR Spectra

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Abstract

Amidation of diphenylphosphorylacetic acid gave tridentate ligands Ph2P(O)CH2CON(R)· CH2CH2P(O)Ph2 (R = Me, Bu, Oct) containing a phosphoryl group in the amide moiety. According to the 1H, 13C{1H}, and 31P{1H} NMR spectra, the synthesized compounds exist in CDCl3 solution as two conformers at the ratios of ~2.5 : 1 (R = Me), 2.6 : 1 (R = Bu), and 3.0:1 (R = Oct). These ratios do not change with temperature (heating or cooling).

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ACKNOWLEDGMENTS

This study was supported by the Ministry of Science and Higher Education of the Russian Federation using the facilities of the joint center at the Kurchatov Institute and Center for Molecular Composition Studies at the Nesmeyanov Institute of Organoelement Compounds (Russian Academy of Sciences).

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Authors and Affiliations

  1. Institute of Chemical Reagents and High Purity Chemical Substances, National Research Center, “Kurchatov Institute”, 107076, Moscow, Russia

    N. A. Bondarenko

  2. National Research Center, “Kurchatov Institute”, 123098, Moscow, Russia

    N. A. Bondarenko & S. K. Belus’

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia

    O. I. Artyushin & A. S. Peregudov

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  1. N. A. Bondarenko
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  2. S. K. Belus’
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  3. O. I. Artyushin
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  4. A. S. Peregudov
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Correspondence to N. A. Bondarenko.

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Bondarenko, N.A., Belus’, S.K., Artyushin, O.I. et al. New Tridentate Carbamoylmethylphosphine Oxides: Synthesis and NMR Spectra. Russ J Gen Chem 90, 2273–2280 (2020). https://doi.org/10.1134/S1070363220120099

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