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Nitroxyl radicals of the imidazoline series as agents of pseudoliving polymerization of styrene

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Abstract

Radical polymerization of styrene in the presence of 2,2,4,5,5-pentamethyl-2,5-dihydro- Imidazol-1-oxyl, 2,2-diethyl-4,5,5-trimethyl-2,5-dihydroimidazol-1-oxyl, 2,2,5,5-tetramethyl- 4-phenyl-2,5-dihydroimidazol-1-oxyl, 2,2,5-trimethyl-4,5-diphenyl-2,5-dihydroimidazol- 1-oxyl, and 2-methyl-2,3-diphenyl-1,4-diazaspiro[4.5]deca-3-en-1-oxyl was studied. Effect of substituents in the nitroxyl radical and the nature of initiator on the features of “pseudoliving” polymerization and the molecular-weight characteristics of polystyrene synthesized were considered. Nitroxyl radicals of imidazoline series, like TEMPO and its derivatives, allow one to regulate polymerization of styrene and obtain polymers with relatively low values of polydispersity index.

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Authors and Affiliations

  1. Scientific Research Institute of Chemistry, N. I. Lobachevsky Nizhnii Novgorod State University, 23, korp. 5 prosp. Gagarina, 603950, Nizhnii Novgorod, Russian Federation

    E. V. Kolyakina, M. A. Lazarev, M. V. Pavlovskaya & D. F. Grishin

  2. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    I. A. Kirilyuk, I. F. Zhurko & I. A. Grigoŕev

Authors
  1. E. V. Kolyakina
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  2. M. A. Lazarev
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  3. M. V. Pavlovskaya
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  4. I. A. Kirilyuk
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  5. I. F. Zhurko
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  6. I. A. Grigoŕev
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  7. D. F. Grishin
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Correspondence to D. F. Grishin.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1519–1527, August, 2010.

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Kolyakina, E.V., Lazarev, M.A., Pavlovskaya, M.V. et al. Nitroxyl radicals of the imidazoline series as agents of pseudoliving polymerization of styrene. Russ Chem Bull 59, 1556–1564 (2010). https://doi.org/10.1007/s11172-010-0278-x

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  • DOI: https://doi.org/10.1007/s11172-010-0278-x

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