Abstract
The enthalpies of formation of nitromethane derivatives were obtained on the basis of experimental and literature data. The procedure for the calculation of the bond dissociation energies in nitromethanes from the atomization enthalpies and energies of nonvalent interactions of nitro groups was proposed. The calculated values were compared with the data on the thermal decomposition kinetics. The atomization enthalpies and energies of nonvalent interactions of nitro groups were also used for the calculation of the bond dissociation energies in radicals.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 755-759, April, 2009.
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Miroshnichenko, E.A., Kon’kova, T.S., Inozemtsev, Y.O. et al. Bond energies and formation enthalpies of mono- and polyradicals in nitroalkanes 1. Nitromethanes. Russ Chem Bull 58, 772–776 (2009). https://doi.org/10.1007/s11172-009-0093-4
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DOI: https://doi.org/10.1007/s11172-009-0093-4