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Determination of enantiomeric purity of 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes by HPLC on chiral stationary phases

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Abstract

A determination of enantiomeric purity of 1-substituted (Me, Ph, and Pri) 3-amino-1,2dicarba-closo-dodecaboranes by HPLC on chiral Chiralcel OD-H and Chiralpac AD stationary phases involving preliminary phthaloylation of 3-aminocarboranes has been suggested as a general method.

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Authors and Affiliations

  1. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22/20 ul. S. Kovalevskoi/Akademicheskaya, 620041, Ekaterinburg, Russian Federation

    V. P. Krasnov, A. M. Demin, G. L. Levit, A. N. Grishakov, L. Sh. Sadretdinova & V. N. Charushin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. A. Ol’shevskaya, I. V. Glukhov & V. N. Kalinin

Authors
  1. V. P. Krasnov
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  2. A. M. Demin
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  3. G. L. Levit
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  4. A. N. Grishakov
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  5. L. Sh. Sadretdinova
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  6. V. A. Ol’shevskaya
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  7. I. V. Glukhov
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  8. V. N. Kalinin
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  9. V. N. Charushin
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Corresponding author

Correspondence to V. P. Krasnov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2484–2488, December, 2008.

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Krasnov, V.P., Demin, A.M., Levit, G.L. et al. Determination of enantiomeric purity of 1-substituted 3-amino-1,2-dicarba-closo-dodecaboranes by HPLC on chiral stationary phases. Russ Chem Bull 57, 2535–2539 (2008). https://doi.org/10.1007/s11172-008-0364-5

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  • DOI: https://doi.org/10.1007/s11172-008-0364-5

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