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Photochemistry of the IrCl6 2− complex in aqueous solutions in the presence of the bromide anions

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Abstract

Laser flash photolysis (308 nm) was applied to study photochemistry of the IrCl6 2− complex in aqueous solutions in the presence of the Br− anions. The formation of the Br2 ·− radical anions in the reaction between the Br− ion and secondary radical pair formed after the photon absorption by the initial complex was observed. The Br2 ·− radical anions decay both in recombination and in the reaction with the initial IrCl6 2− complex.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. M. Glebov & V. F. Plyusnin

  2. Institute of Materials Chemistry, Tampere University of Technology, P.O. Box 589, FIN-33101, Tampere, Finland

    N. V. Tkachenko & H. Lemmetyinen

Authors
  1. E. M. Glebov
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  2. V. F. Plyusnin
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  3. N. V. Tkachenko
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  4. H. Lemmetyinen
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Corresponding author

Correspondence to E. M. Glebov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2437–2444, December, 2008.

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Glebov, E.M., Plyusnin, V.F., Tkachenko, N.V. et al. Photochemistry of the IrCl6 2− complex in aqueous solutions in the presence of the bromide anions. Russ Chem Bull 57, 2487–2494 (2008). https://doi.org/10.1007/s11172-008-0358-3

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  • DOI: https://doi.org/10.1007/s11172-008-0358-3

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