Abstract
The formation of cadmium sulfide nanoparticles upon UV irradiation of aqueous solutions of cadmium thiosulfates was established on the basis of spectroscopic and macroscopic data. The yield and size of the cadmium sulfide nanoparticles depend on the ratio of cadmium to thiosulfate ions in solution, the concentration of the solution, and the irradiation duration. The cadmium sulfide nanoparticles with a diameter of 4 nm were obtained by the photolysis of solutions with a concentration of 10−3 mol L−1 at the ratio S2O3 2−: Cd2+ = 2: 1.
Similar content being viewed by others
References
A. I. Gusev, A. A. Rempel’, Nanokristallicheskie materialy [Nanocrystalline Materials], Fizmatlit, Moscow, 2000, 224 pp. (in Russian).
B. I. Lemon, R. Crooks, J. Am. Chem. Soc., 2000, 122, 12866.
L. Z. Yao, C. H. Ye, C. M. Mo, Y. Zhang, L. D. Zhang, Chinese Chem. Lett., 2000, 11, 627.
M. C. Brelle, J. C. Menulty, R. K. Mehra, J. Z. Zhang, Pure Appl. Chem., 2000, 72, 101.
C. M. Simonescu, V. S. Teodorescu, O. Carp, L. Patron, C. Capatina, J. Therm. Anal. Cal., 2007, 88, 71.
G. Wang, G. Li, C. Liang, L. Zhang, Chem. Lett., 2001, 30, 344.
Y. J. Yang, L. Y. He, Electrochim. Acta, 2005, 50, 3581.
M. Marandi, N. Taghavinia, A. Irajizad, M. Mahadavi, Nanotechnology, 2006, 17, 1230.
T. Ding, J. Zhang, S. Long, J. Zhu, Microelectron. Eng., 2003, 66, 46.
N. Yonghong, G. Xuewu, L. Huarong, Z. Zhicheng, Y. Qiang, Chem. Lett., 2001, 30, 924.
A. A. Nemodruk, E. V. Bezrogova, Fotokhimicheskie reaktsii v analiticheskoi khimii [Photochemical Reactions in Analytical Chemistry], Khimiya, Moscow, 1972, 167 pp. (in Russian).
Photochemistry, Eds J. G. Calvert, J. N. Pitts, Wiley, New York, 1966.
L. P. Eremin, N. L. Eremina, Vestn. Tomsk. gos. ped. un-ta. Ser. Estestvennye i tochnye nauki [Bull. Tomsk State Pedagogical Univ., Ser. Natural Exact Science], 1999, 7, 62 (in Russian).
Die Komplexometrische Titration, Eds G. Schwarzenbach, H. Flaschka, Ferdinand enke Verlag, Stuttgart, 1965.
A. I. Busev, L. N. Simonova, Analiticheskaya khimiya sery [Analytical Chemistry of Sulfur], Nauka, Moscow, 1975, 272 pp. (in Russian).
L. N. Mirkin, Spravochnik po rentgenostrukturnomu analizu polikristallov [Manual on X-ray Structure Analysis of Polycrystals], Fizmatlit, Moscow, 1961, p. 466 (in Russian).
S. D. Wu, Z. Zhu, J. Tan, J. Gao, Chem. Lett., 2001, 30, 396.
T. Torimoto, H. Kontani, T. Sakata, H. Mori, H. Yoneyama, Chem. Lett., 1999, 5, 379.
Yu. Yu. Luré, Spravochnik po analiticheskoi khimii [Manual on Analytical Chemistry], Khimiya, Moscow, 1979, p. 336 (in Russian).
Ionic Equilibrium (A Mathematical Approach), Ed. J. N. Butler, Reading, Massachusetts, 1964.
R. F. Khairutdinov, Usp. Khim., 1998, 67, 125 [Russ. Chem. Rev., 1998, 67 (Engl. Transl.)].
W. William Yu, Lianhua Qu, Wenzhuo Guo, Xiaogang Peng, Chem. Mater., 2003, 15, 2854.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2433–2436, December, 2008.
Rights and permissions
About this article
Cite this article
Egorov, N.B., Eremin, L.P., Larionov, A.M. et al. Photochemical synthesis of cadmium sulfide nanoparticles. Russ Chem Bull 57, 2483–2486 (2008). https://doi.org/10.1007/s11172-008-0357-4
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11172-008-0357-4