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Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+

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Abstract

The benzene complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3a) was synthesized by the photochemical reaction of [(η5-C6H7)Fe(η-C6H6)]+ (1) with the anion [7-ButNH-7,8,9-C3B8H10]− followed by the treatment of ferracarborane 1-(η5-C6H7)-12-ButNH-1,2,4,12-FeC3B8H10 (2) with hydrochloric acid. The benzene ligand in cation 3a is replaced by alkyl-substituted benzenes under visible light irradiation in CH2Cl2 to form [1-(η-C6R6)-12-ButNH-1,2,4,12-FeC3B8H10]+ (3b–e; C6R6 is toluene (b), mesitylene (c), hexamethylbenzene (d), or anisole (e)). The structure of [3c]PF6 was established by X-ray diffraction.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    D. A. Loginov, M. M. Vinogradov, Z. A. Starikova, P. V. Petrovskii & A. R. Kudinov

  2. Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Research Centre for New Inorganic Compounds and Advanced Materials, University of Pardubice, 25068, Řež, Czech Republic

    J. Holub

Authors
  1. D. A. Loginov
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  2. M. M. Vinogradov
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  3. Z. A. Starikova
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  4. P. V. Petrovskii
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  5. J. Holub
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  6. A. R. Kudinov
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Correspondence to A. R. Kudinov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2250–2252, November, 2008.

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Loginov, D.A., Vinogradov, M.M., Starikova, Z.A. et al. Photochemical arene exchange in the ferracarborane complex [1-(η-C6H6)-12-ButNH-1,2,4,12-FeC3B8H10]+ . Russ Chem Bull 57, 2294–2297 (2008). https://doi.org/10.1007/s11172-008-0324-0

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  • DOI: https://doi.org/10.1007/s11172-008-0324-0

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