Abstract
The allylation of prochiral C-nucleophiles catalyzed by the Pd(0)—(S)-(—)-BINAP complex (BINAP is 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) was studied. The enantioselectivity of the allylation was found to be low.
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References
B. M. Trost, Tetrahedron, 1977, 33, 2615.
B. M. Trost, D. L. Van Vranken, Chem. Rev., 1996, 96, 395.
A. V. Lozanova, T. M. Ugurchieva, M. V. Zlokazov, A. V. Stepanov, V. V. Veselovsky, Mendeleev Commun., 2006, 15
A. V. Lozanova, T. M. Ugurchieva, V. V. Veselovskii, Izv. Akad. Nauk, Ser. Khim., 2007, 124 [Russ. Chem. Bull., Int. Ed., 2007, 56, 130].
J. Tsuji, I. Shimizu I. Minami, Y. Ohashi, T. Sugiura, K. Takahashi, J. Org. Chem., 1985, 50, 1523.
T. M. Ugurchieva, A. V. Lozanova, M. V. Zlokazov, V. V. Veselovsky, Izv. Akad. Nauk, Ser. Khim., 2007, 1485 [Russ. Chem. Bull., Int. Ed., 2007, 56, 1544].
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1753—1755, August, 2008.
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Lozanova, A.V., Ugurchieva, T.M. & Veselovsky, V.V. Allylation of prochiral C-nucleophiles catalyzed by the Pd(0)—(S)-(—)-BINAP complex. Russ Chem Bull 57, 1787–1789 (2008). https://doi.org/10.1007/s11172-008-0239-9
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DOI: https://doi.org/10.1007/s11172-008-0239-9