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One-pot process in phosphonium-iodonium ylides: nucleophilic substitution and the Wittig reaction

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Abstract

The nucleophilic substitution in mixed phosphonium-iodonium ylides was investigated. The iodonium group is replaced by such S-containing nucleophiles as the thiocyanate anion or thiourea, as well as by halide ions. The structure of the reaction product with the thiocyanate ion was established by X-ray diffraction. A one-pot process involving the nucleophilic substitution and the Wittig reaction was developed.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. D. Matveeva, T. A. Podrugina, A. S. Pavlova, A. V. Mironov & N. S. Zefirov

Authors
  1. E. D. Matveeva
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  2. T. A. Podrugina
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  3. A. S. Pavlova
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  4. A. V. Mironov
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  5. N. S. Zefirov
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Corresponding author

Correspondence to E. D. Matveeva.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 391–395, February, 2008.

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Matveeva, E.D., Podrugina, T.A., Pavlova, A.S. et al. One-pot process in phosphonium-iodonium ylides: nucleophilic substitution and the Wittig reaction. Russ Chem Bull 57, 400–405 (2008). https://doi.org/10.1007/s11172-008-0061-4

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  • DOI: https://doi.org/10.1007/s11172-008-0061-4

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