Abstract
Ethynyl-substituted nitronyl nitroxide is involved in the 1,3-dipolar cycloaddition with cyclic nitrones without affecting the nitronyl nitroxide fragment. The reaction of 2,4,4,5,5-pentamethyl-4,5-dihydro-1H-imidazole 3-oxide produces the corresponding 1,2,3,7a-tetrahydroimidazo[1,2-b]isoxazole derivative. The analog of the latter derived from 4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole 3-oxide is transformed into spin-labeled aminoenal. The solid phase of aminoenal is formed by packing unsymmetrical trimers resulting from the self-assembling of the molecular fragments based on a hydrogen bond network.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
E. Tretyakov, G. Romanenko, A. Podoplelov, and V. Ovcharenko, Eur. J. Org. Chem., 2006, 2695.
E. Tretyakov, G. Romanenko, V. Ikorskii, D. Stass, V. Vasiliev, M. Demina, A. Mareev, A. Medvedeva, and V. Ovcharenko, Eur J. Org. Chem., 2007, 3639.
R. C. F. Jones, J. N. Martin, P. Smith, T. Gelbrich, M. E. Light, and M. B. Hursthouse, Chem. Commun., 2000, 19, 1949.
R. C. F. Jones, J. N. Martin, and P. Smith, J. Heterocycl. Chem., 2000, 37, 481.
V. A. Reznikov, G. I. Roshchupkina, D. G. Mazhukin, P. A. Petrov, S. A. Popov, S. V. Fokin, G. V. Romanenko, T. V. Rybalova, Y. V. Gatilov, Y. G. Shvedenkov, I. G. Irtegova, L. A. Shundrin, and V. I. Ovcharenko, Eur. J. Org. Chem., 2004, 749.
S. A. Popov, N. V. Chukanov, G. V. Romanenko, T. V. Rybalova, Y. V. Gatilov, and V. A. Reznikov, J. Heterocycl. Chem., 2006, 43, 277.
F. B. Sviridenko, D. V. Stass, T. V. Kobzeva, E. V. Tretyakov, S. V. Klyatskaya, E. V. Mshvidobadze, S. F. Vasilevsky, and Yu. N. Molin, J. Am. Chem. Soc., 2004, 126, 2807.
E. V. Tretyakov, G. V. Romanenko, and V. I. Ovcharenko, Izv. Akad. Nauk, Ser. Khim., 2006, 570 [Russ. Chem. Bull., Int. Ed., 2006, 55, 591].
S. A. Popov, R. V. Andreev, G. V. Romanenko, V. I. Ovcharenko, and V. A. Reznikov, J. Mol. Struct., 2004, 697, 49.
P. A. Petrov, S. V. Fokin, G. V. Romanenko, Y. G. Shvedenkov, V. A. Reznikov, and V. I. Ovcharenko, Mendeleev Commun., 2001, 179.
Author information
Authors and Affiliations
Corresponding author
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1975–1979, October, 2007.
Rights and permissions
About this article
Cite this article
Tretyakov, E.V., Ovcharenko, V.I., Sagdeev, R.Z. et al. New type of spin-labeled aminoenal. Russ Chem Bull 56, 2043–2047 (2007). https://doi.org/10.1007/s11172-007-0319-2
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-007-0319-2