Abstract
The variation of the microscopic properties (surface potential, micropolarity, etc.) of the interface of cetyltrimethylammonium bromide micelles upon the addition of a background electrolyte or the nonionic surfactant Triton X-100 decreases the rates of ion-molecular reactions, namely, alkaline hydrolysis of carboxylic acid esters and tetracoordinate phosphorus acid esters, and results in the shift of acid-base equilibria.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1933–1940, October, 2007.
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Mirgorodskaya, A.B., Zakharova, L.Y., Valeeva, F.G. et al. Control of the catalytic effect of cetyltrimethylammonium bromide micelles by the addition of background electrolyte and nonionic surfactant. Russ Chem Bull 56, 2000–2007 (2007). https://doi.org/10.1007/s11172-007-0312-9
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DOI: https://doi.org/10.1007/s11172-007-0312-9