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Temperature effect on the volume properties of a bisurea aqueous solutions

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Abstract

The densities of aqueous solutions of bisurea (2,4,6,8-tetraazabicyclo[3.3.0]octane-3,7-dione) were measured using a vibrating-tube densimeter at 288.15, 298.15, 308.15, and 318.15 K in the concentration range up to ∼3·10−3 moles of solute (1000 g of H2O)−1 with the error at most ±5· 10−6 g cm−3 (reproducibility up to 2·10−6 g cm−3). The limiting partial molar volume and expansibility of bisurea in water were calculated. The bicyclic molecules under study form in aqueous solution H-bonded hydrate complexes with rather high structure-packing density. These complexes are more subjected to the destroying effect of temperature than the corresponding urea complexes. The hydration of bisurea weakens with the temperature increase.

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Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, 1 ul. Akademicheskaya, 153045, Ivanovo, Russian Federation

    E. V. Ivanov, V. K. Abrosimov & E. Yu. Lebedeva

  2. V. I. Lenin Ivanovo State Energy University, 34 Rabfakovskaya, 153003, Ivanovo, Russian Federation

    V. K. Abrosimov & N. G. Ivanova

Authors
  1. E. V. Ivanov
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  2. V. K. Abrosimov
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  3. N. G. Ivanova
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  4. E. Yu. Lebedeva
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Correspondence to E. V. Ivanov.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1929–1932, October, 2007.

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Ivanov, E.V., Abrosimov, V.K., Ivanova, N.G. et al. Temperature effect on the volume properties of a bisurea aqueous solutions. Russ Chem Bull 56, 1996–1999 (2007). https://doi.org/10.1007/s11172-007-0311-x

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  • DOI: https://doi.org/10.1007/s11172-007-0311-x

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