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Liquid-phase noncatalytic oxidation of monoterpenoids with nitrous oxide

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Abstract

A series of monoterpenoids differing in the number of double bonds and the pattern of their substitution were tested in the liquid-phase noncatalytic oxidation with nitrous oxide (N2O). The structure of olefins has a significant effect on the oxidation route. In the case of terpenoids containing 1,1-disubstituted double bond, nor-carbonyl compounds are formed with high selectivity.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    E. P. Romanenko & A. V. Tkacheva

  2. G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 5 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    E. V. Starokon’ & G. I. Panov

  3. Novosibirsk State University, 2 ul. Pirogova, 630090, Novosibirsk, Russian Federation

    A. V. Tkacheva

Authors
  1. E. P. Romanenko
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  2. E. V. Starokon’
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  3. G. I. Panov
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  4. A. V. Tkacheva
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Correspondence to A. V. Tkacheva.

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Dedicated to the memory of Academician N. N. Vorozhtsov on the 100th anniversary of his birth.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1193–1197, June, 2007.

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Romanenko, E.P., Starokon’, E.V., Panov, G.I. et al. Liquid-phase noncatalytic oxidation of monoterpenoids with nitrous oxide. Russ Chem Bull 56, 1239–1243 (2007). https://doi.org/10.1007/s11172-007-0187-9

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  • DOI: https://doi.org/10.1007/s11172-007-0187-9

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