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Synthesis of salicylaldehydes bearing bulky substituents in the positions 3 and 5

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Russian Chemical Bulletin Aims and scope

Abstract

Reaction of 2,4-disubstituted phenols with paraformaldehyde in the presence of SnCl4 and 2,6-lutidine afforded a number of new salicylaldehydes, containing bulky substituents (tert-butyl, 1-phenylethyl, 1-(4-tert-butylphenyl)ethyl, α-cumyl, and trityl) in the positions 3 and 5.

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    A. I. Kochnev, I. I. Oleynik, I. V. Oleynik & G. A. Tolstikov

  2. St. Petersburg Division, G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, 6 Birzhevoi proezd, 199004, St. Petersburg, Russian Federation

    S. S. Ivanchev

Authors
  1. A. I. Kochnev
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  2. I. I. Oleynik
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  3. I. V. Oleynik
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  4. S. S. Ivanchev
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  5. G. A. Tolstikov
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Correspondence to I. I. Oleynik.

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Dedicated to the memory of Academician N. N. Vorozhtsov on the 100th anniversary of his birth.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1084–1088, June, 2007.

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Kochnev, A.I., Oleynik, I.I., Oleynik, I.V. et al. Synthesis of salicylaldehydes bearing bulky substituents in the positions 3 and 5. Russ Chem Bull 56, 1125–1129 (2007). https://doi.org/10.1007/s11172-007-0170-5

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  • DOI: https://doi.org/10.1007/s11172-007-0170-5

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