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Synthesis and structure of the framework coordination polymer based on the cluster anion [Nb4OTe4(CN)12]6− and MnII aqua complexes

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Abstract

Dark-brown plate crystals of the [Mn7(H2O)26{Nb4OTe4(CN)12} 2](OH)2·11H2O compound (1) were prepared by the reaction of an aqueous ammonia solution of the K6[Nb4OTe4(CN)12]{K2CO3{KOH{8H2O complex with a glycerol solution of manganese(II) nitrate. The structure of complex 1 was established by X-ray diffraction. Compound 1 has a polymer structure containing four types of manganese atoms. The nitrogen atoms of eight cyano groups of the tetranuclear niobium cluster are coordinated to the manganese atoms to form a {2,3,8}-connected three-dimensional network.

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References

  1. K. R. Dunbar and R. A. Heintz, Prog. Inorg. Chem., 1997, 45, 283.

    Article  CAS  Google Scholar 

  2. T. Iwamoto, in Comprehensive Supramolecular Chemistry, Eds J. L. Atwood, J. E. D. Davies, D. D. Macnicol, and F. Vögtle, Pergamon, Oxford, 1996, 6, 643.

    Google Scholar 

  3. B. H. Chadwick and A. G. Sharpe, Adv. Inorg. Chem. Radiochem., 1966, 8, 83.

    CAS  Google Scholar 

  4. I. V. Tananaev, G. B. Seifer, Yu. Ya. Kharitonov, V. G. Kuznetsov, and A. P. Korol’kov, Khimiya ferrotsianidov [Chemistry of Ferrocyanides], Nauka, Moscow, 1971, pp. 320 (in Russian).

    Google Scholar 

  5. N. G. Naumov, A. V. Virovets, and V. E. Fedorov, Zh. Strukt. Khim., 2000, 41, 609 [Russ. J. Struct. Chem., 2000, 41 (Engl. Transl.)].

    Google Scholar 

  6. N. G. Naumov, A. V. Virovets, M. N. Sokolov, S. B. Artemkina, and V. E. Fedorov, Angew. Chem., Int. Ed., 1998, 37, 1943.

    Article  CAS  Google Scholar 

  7. N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov, J. Solid State Chem., 2000, 153, 195.

    Article  CAS  Google Scholar 

  8. N. G. Naumov, A. V. Virovets, and V. E. Fedorov, Inorg. Chem. Commun., 2000, 3, 71.

    Article  CAS  Google Scholar 

  9. Yu. V. Mironov, A. V. Virovets, S. B. Artemkina, and V. E. Fedorov, Angew. Chem., Int. Ed., 1998, 37, 2507.

    Article  CAS  Google Scholar 

  10. Yu. V. Mironov, A. V. Virovets, W. S. Sheldrick, and V. E. Fedorov, Polyhedron, 2001, 20, 969.

    Article  CAS  Google Scholar 

  11. Yu. V. Mironov, V. E. Fedorov, I. Ijjaali, and J. A. Ibers, Inorg. Chem., 2001, 40, 6320.

    Article  CAS  Google Scholar 

  12. Yu. V. Mironov, O. A. Efremova, D. Yu. Naumov, W. S. Sheldrick, and V. E. Fedorov, Eur. J. Inorg. Chem., 2003, 2591.

  13. V. P. Fedin, I. V. Kalinina, A. V. Gerasimenko, and A. V. Virovets, Inorg. Chim. Acta, 2002, 331, 48.

    Article  CAS  Google Scholar 

  14. V. P. Fedin, I. V. Kalinina, A. V. Virovets, and D. Fenske, Izv. Akad. Nauk, Ser. Khim., 2003, 119 [Russ. Chem. Bull., Int. Ed., 2003, 52, 126].

    Google Scholar 

  15. V. P. Fedin, A. V. Virovets, I. V. Kalinina, V. N. Ikorskii, M. R. J. Elsegood, and W. Clegg, Eur. J. Inorg. Chem., 2000, 2341.

  16. V. P. Fedin, I. V. Kalinina, A. V. Virovets, and D. Fenske, Izv. Akad. Nauk, Ser. Khim., 2001, 1451 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1525].

    Google Scholar 

  17. I. V. Kalinina, D. G. Samsonenko, V. A. Nadolinnyi, Ya. Lipkovski, and V. P. Fedin, Izv. Akad. Nauk, Ser. Khim., 2004, 86 [Russ. Chem. Bull., Int. Ed., 2004, 53, 86].

    Google Scholar 

  18. I. V. Kalinina, A. V. Virovets, F. M. Dolgushin, M. Yu. Antipin, R. Llusar, and V. P. Fedin, Inorg. Chim. Acta, 2004, 357, 3390.

    Article  CAS  Google Scholar 

  19. O. A. Efremova, Yu. V. Mironov, and V. E. Fedorov, Eur. J. Inorg. Chem., 2006, 2533.

  20. I. V. Kalinina and V. P. Fedin, Koord. Khim., 2003, 29, 643 [Russ. J. Coord. Chem., 2003, 29 (Engl. Transl.)].

    Google Scholar 

  21. V. P. Fedin, I. V. Kalinina, A. V. Virivets, N. V. Podberezskaya, I. S. Neretin, and Yu. L. Slovokhotov, Chem. Commun., 1998, 2579.

  22. V. P. Fedin, I. V. Kalinina, A. V. Virovets, and D. Fenske, Izv. Akad. Nauk, Ser. Khim., 2001, 892 [Russ. Chem. Bull., Int. Ed., 2001, 50, 930].

    Google Scholar 

  23. A. F. Wells, Three-dimensional Nets and Polyhedra, Wiley, New York, 1977.

    Google Scholar 

  24. M. O’Keeffe, M. Eddaoudi, H. Li, T. Reineke, and O. M. Yaghi, J. Solid State Chem., 2000, 152, 3.

    Article  CAS  Google Scholar 

  25. V. A. Blatov, L. Carlucci, G. Ciani, and D. M. Proserpio, Cryst. Eng. Commun., 2004, 6, No 65, 377.

    CAS  Google Scholar 

  26. I. A. Baburin, V. A. Blatov, L. Carlucci, G. Ciani, and D. M. Proserpio, J. Solid State Chem., 2005, 178, 2471.

    Article  Google Scholar 

  27. V. A. Blatov and Yu. A. Zakutkin, Z. Kristallogr., 2002, 217, 464.

    Article  CAS  Google Scholar 

  28. G. D. Ilyushin, V. A. Blatov, and Y. A. Zakutkin, Z. Kristallogr., 2004, 219, 468.

    Article  CAS  Google Scholar 

  29. G. D. Ilyushin, V. A. Blatov, and Y. A. Zakutkin, Acta Crystallogr., Sect. B, 2002, 58, 948.

    Article  CAS  Google Scholar 

  30. APEX2 v. 1.08, SAINT v. 7.03, SADABS v. 2.11. Bruker Advanced X-ray Solutions, Bruker AXS Inc., Madison (Wisconsin, USA), 2004.

  31. SHELXTL v. 6.22. Bruker Advanced X-ray Solutions, Bruker AXS Inc., Madison (Wisconsin, USA), 2005.

  32. V. A. Blatov, A. P. Shevchenko, and V. N. Serezhkin, J. Appl. Crystallogr., 2000, 33, 1193.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    I. V. Kalinina, A. V. Virovets & V. P. Fedin

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  1. I. V. Kalinina
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  2. A. V. Virovets
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  3. V. P. Fedin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 224–228, February, 2007.

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Kalinina, I.V., Virovets, A.V. & Fedin, V.P. Synthesis and structure of the framework coordination polymer based on the cluster anion [Nb4OTe4(CN)12]6− and MnII aqua complexes. Russ Chem Bull 56, 231–235 (2007). https://doi.org/10.1007/s11172-007-0038-8

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  • DOI: https://doi.org/10.1007/s11172-007-0038-8

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