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One Three-Dimensional {Mn4} Cluster Coordination Polymer from a New Tetracarboxylate Linker and N-Donor Ancillary Ligand: Crystal Structure and Magnetic Property

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Abstract

Hydrothermal reactions of biphenyl-2,3,3′,5′-tetracarboxylic acid (H4bptc) with manganese salt in the presence of 1,4-bis(2-pyridylmethyl)piperazine (bpmp) afforded one novel coordination polymer, namely, [Mn2(bptc)(bpmp)0.5]n (1). Its structure was established by single-crystal X-ray diffraction analysis and further characterized by elemental analysis, IR spectra and TG analysis. Complex 1 contains {Mn4} cluster, exhibiting an unusual mode of two-fold interpenetrating three-dimensional (3D) framework with a (3, 8)-connected (84.102) (4.7.84.102.11.15) topology. In addition, magnetic susceptibility measurements indicate that complex 1 show weak antiferromagnetic interactions between the adjacent manganese ions.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21273101 and 21302082), Program for Science & Technology Innovation Talents (2014HASTIT014) and Research Team in Universities of Henan (4IRTSTHN008), and Tackle Key Problem of Science and Technology Project of Henan Province, China (No. 142102310483), and Key program of the Foundation of Education Committee of Henan Province (No. 14B150033).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang, 471022, Henan, China

    Rong-Fang Li, Xin-Fang Liu, Yu-Fang Wang, Tian Zhang & Xun Feng

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  1. Rong-Fang Li
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  2. Xin-Fang Liu
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  3. Yu-Fang Wang
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  4. Tian Zhang
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  5. Xun Feng
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Correspondence to Rong-Fang Li or Xun Feng.

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Li, RF., Liu, XF., Wang, YF. et al. One Three-Dimensional {Mn4} Cluster Coordination Polymer from a New Tetracarboxylate Linker and N-Donor Ancillary Ligand: Crystal Structure and Magnetic Property. J Inorg Organomet Polym 25, 1200–1204 (2015). https://doi.org/10.1007/s10904-015-0228-z

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  • DOI: https://doi.org/10.1007/s10904-015-0228-z

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