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Design of scaffold-like metal-organic coordination polymers based on dinuclear zinc(II) carboxylate complexes

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Abstract

Two new scaffold-like metal-organic coordination polymers, [Zn2ndc2bpe]·DMF and [Zn2ndc2dedpbp] ·4DMF (ndc is 2,6-naphthalenedicarboxylate, bpe is trans-bis(4-pyridyl)ethylene, and dedpbp is 4,4′-diethynyl-4″,4′″-dipyridylbiphenyl), were synthesized by heating stoichiometric amounts of zinc(II) nitrate, H2ndc, and bpe or dedpbp in DMF. The structures of the polymers were established by X-ray diffraction. Coordination of linear dicarboxylate ligands to zinc cations gives rise to planar square-grid networks, and additional coordination of the bifunctional nitrogen-containing ligands results in the formation of scaffold-like triply interpenetrating structures with a primitive cubic topology.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    D. N. Dybtsev, E. V. Peresypkina & V. P. Fedin

  2. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Sciences, 3 ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    I. E. Sokolov

Authors
  1. D. N. Dybtsev
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  2. I. E. Sokolov
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  3. E. V. Peresypkina
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  4. V. P. Fedin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 219–223, February, 2007.

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Dybtsev, D.N., Sokolov, I.E., Peresypkina, E.V. et al. Design of scaffold-like metal-organic coordination polymers based on dinuclear zinc(II) carboxylate complexes. Russ Chem Bull 56, 225–230 (2007). https://doi.org/10.1007/s11172-007-0037-9

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  • DOI: https://doi.org/10.1007/s11172-007-0037-9

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