Abstract
The adsorption of rod-like molecules in slit-shaped pores was considered within the frame-work of the lattice-gas model. This model is applicable over a broad range of fluid concentrations (from the gaseous to the liquid state) and temperatures (including the critical region). In the calculation of the local distributions of mixture components in the equilibrium states, lateral interactions are taken into account. The equations of the model reflect the strong anisotropy of the distribution of mixture components along the normal to the pore wall surface and ordering of the rods along various directions.
Similar content being viewed by others
References
D. P. Timofeev, Kinetika adsorbtsii [Adsorption Kinetics], Izd-vo AN SSSR, Moscow, 1962, 252 pp. (in Russian).
C. N. Satterfield, Mass Transfer in Heterogeneous Catalysis, MIT Press, Cambridge (Mass.), 1970.
E. A. Mason and A. P. Malinauskas, Gas Transport in Porous Media: The Dusty-Gas Model, Elsevier, Amsterdam, 1983.
Yu. K. Tovbin, in Sovremennoe sostoyanie i perspektivy razvitiya teorii adsorbtsii (Materialy konferentsii, posvyashchennoi 100-letiyu M. M. Dubinina) [Current State and Prospects of Development of the Adsorption Theory (Proc. Conf. Dedicated to the 100th Anniversary of M. M. Dubinin’s Birthday)], Institute of Physical Chemistry of the RAS, Moscow, 2001, 27 (in Russian).
Yu. K. Tovbin, Teoriya fiziko-khimicheskikh protsessov na granitse gaz—tverdoe telo [Theory of Physicochemical Processes at the Gas—Solid Interface], Nauka, Moscow, 1990, 288 pp. (in Russian).
Yu. K. Tovbin, Izv. Akad. Nauk. Ser. Khim., 1999, 1467 [Russ. Chem. Bull., 1999, 48, 1450 (Engl. Transl.)].
Yu. K. Tovbin, L. K. Zhidkova, and V. N. Komarov, Izv. Akad. Nauk. Ser. Khim., 2001, 752 [Russ. Chem. Bull., Int. Ed., 2001, 50, 786].
N. A. Smirnova, Molekulyarnaya teoriya rastvorov [Molecular Theory of Solutions], Khimiya, Leningrad, 1987, 360 pp. (in Russian).
S. Chandrasekhar, Liquid Crystals, Cambridge Univer. Press, Cambridge, 1977.
I. P. Bazarov and E. V. Gevorkyan, Statisticheskaya teoriya tverdykh i zhidkikh crystallov [Statistical Theory of Solid and Liquid Crystals], Izd. MGU, Moscow, 1983, 262 pp. (in Russian).
J. O. Hirschfelder, C. F. Curtiss, and R. B. Bird, Molecular Theory of Gases and Liquids, Wiley, New York, 1954.
A. V. Kiselev, Mezhmoleculyarnye vzaimodeistviya v adsorbtsii i khromatografii [Intermolecular Interactions in Adsorption and Chromatography], Vysshaya shkola, Moscow, 1986, 360 pp. (in Russian).
W. A. Steele, The Interactions of Gases with Solid Surfaces, Pergamon, New York, 1974.
Yu. K. Tovbin, Dokl. Akad. Nauk, 1995, 345, 639 [Dokl. Chem., 1995 (Engl. Transl.)].
J. A. Barker, J. Chem. Phys., 1952, 20, 1528.
E. AS. DiMarzio, J. Chem. Phys., 1961, 35, 658.
K. Yoon, D. G. Chae, T. Ree, and F. H. Ree, J. Chem. Phys., 1981, 74, 1412.
J. Herzfeld, J. Chem. Phys., 1982, 76, 4185.
Yu. K. Tovbin and A. B. Rabinovich, Izv. Akad. Nauk. Ser. Khim., 2006, 1485 [Russ. Chem. Bull., Int. Ed., 2006, 55, 1539].
Author information
Authors and Affiliations
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1476–1484, September, 2006.
Rights and permissions
About this article
Cite this article
Tovbin, Y.K., Rabinovich, A.B. Calculation of the adsorption of rod-like molecules in narrow slit-shaped pores. Russ Chem Bull 55, 1530–1538 (2006). https://doi.org/10.1007/s11172-006-0451-4
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-006-0451-4