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Calculation of the adsorption of rod-like molecules in narrow slit-shaped pores

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Abstract

The adsorption of rod-like molecules in slit-shaped pores was considered within the frame-work of the lattice-gas model. This model is applicable over a broad range of fluid concentrations (from the gaseous to the liquid state) and temperatures (including the critical region). In the calculation of the local distributions of mixture components in the equilibrium states, lateral interactions are taken into account. The equations of the model reflect the strong anisotropy of the distribution of mixture components along the normal to the pore wall surface and ordering of the rods along various directions.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1476–1484, September, 2006.

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Tovbin, Y.K., Rabinovich, A.B. Calculation of the adsorption of rod-like molecules in narrow slit-shaped pores. Russ Chem Bull 55, 1530–1538 (2006). https://doi.org/10.1007/s11172-006-0451-4

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  • DOI: https://doi.org/10.1007/s11172-006-0451-4

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