Abstract
Solid-phase thermal decomposition of polynuclear NiII and CoII pivalate complexes was studied by differential scanning calorimetry and thermogravimetry. The decomposition of the polynuclear (from bi-to hexanuclear) CoII carboxylate complexes is accompanied by aggregation to form a volatile octanuclear complex. Thermolysis of the polynuclear NiII carboxylates results in their destructure, and the phase composition of the decomposition products is determined by the nature of coordinated ligands.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 250—260, February, 2006.
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Dobrokhotova, Z.V., Fomina, I.G., Kiskin, M.A. et al. Solid-phase thermal decomposition of polynuclear nickel(II) and cobalt(II) complexes. Russ Chem Bull 55, 256–266 (2006). https://doi.org/10.1007/s11172-006-0246-7
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DOI: https://doi.org/10.1007/s11172-006-0246-7