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Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx

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Abstract

Nickel(II) complexes of the composition [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3) have been synthesized and studied. The thermal reduction of the complexes has been studied in the temperature range 20–800°C in air and in an inert atmosphere. Precursor complexes and their reduction products have been identified by elemental analysis, X-ray powder diffraction, and IR spectroscopy. The physicochemical study of the thermolysis product of complex [Ni(DMF)6][B10H10] shows that scarcely studied solid solutions of the composition Ni3C1 –xВx are formed.

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ACKNOWLEDGMENTS

Analytical studies were carried out at the Center for Collective Use of the Kurchatov Institute.

Funding

This work was carried out as part of the State Assignment to the Kurnakov Institute in the field of fundamental scientific research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    E. A. Malinina, L. V. Goeva, G. A. Buzanov, V. V. Avdeeva & N. T. Kuznetsov

  2. Institute for Chemical Reagents and High Purity Chemical Substances, National Research Center “Kurchatov Institute”, 107076, Moscow, Russia

    V. M. Retivov

Authors
  1. E. A. Malinina
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  2. L. V. Goeva
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  3. G. A. Buzanov
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  4. V. M. Retivov
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  5. V. V. Avdeeva
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  6. N. T. Kuznetsov
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Correspondence to V. V. Avdeeva.

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Translated by V. Avdeeva

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Malinina, E.A., Goeva, L.V., Buzanov, G.A. et al. Synthesis and Thermal Reduction of Complexes [NiLn][B10H10] (L = DMF, H2O, n = 6; L = N2H4, n = 3): Formation of Solid Solutions Ni3C1 –xВx. Russ. J. Inorg. Chem. 65, 126–132 (2020). https://doi.org/10.1134/S0036023620010118

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