Skip to main content
SpringerLink
Log in

Rhenium(IV) and rhenium(V) complexes with 3,5-dimethylpyrazole

  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Mono-and dinuclear ReIV and ReV complexes with 3,5-dimethylpyrazole (Me2pzH) were synthesized. The cis-[Re2O3Cl4(3,5-Me2pzH)4] complex (cis-1) was prepared by the reaction of NH4ReO4 with K[HB(Me2pz)3] in concentrated HCl or by refluxing of [ReCl3(MeCN)(PPh3)2] with Me2pzH in air. The bromide complex trans-[Re2O3Br4(3,5-Me2pzH)4] (trans-2) was synthesized by passing dry HBr through a solution of [Re2O3Br2(μ-3,5-Me2pz)2(3,5-Me2pzH)2] (4) in chloroform. The pyrazolate-bridged complex [Re2O3Cl2(μ-3,5-Me2pz)2(3,5-Me2pzH)2] (3) was prepared from (Et4N)2[ReOCl5] or Cs2[ReOCl5] and Me2pzH. The corresponding bromide and iodide complexes [Re2O3X2(3,5-Me2pz)2(3,5-Me2pzH)2] · C6H6 (X = Br (4) or I (5)) were synthesized by the reactions of (NH4)2[ReBr6] or K2[ReI6], respectively, with Me2pzH. The [ReO(OMe)(3,5-Me2pzH)4]Br2 · · 3,5-Me2pzH · 4H2O complex (6) was obtained as a by-product in the synthesis of complex 4. The reaction of [ReNCl2(PPh3)2] with Me2pzH was accompanied by hydrolytic denitration giving rise to the mixed-ligand complex [Re2O3Cl2(μ-3,5-Me2pz)2(3,5-Me2pzH)(PPh3)] (7). The reaction of (NH4)2[ReBr6] with a Me2pzH melt gave the trans-[ReBr4(3,5-Me2pzH)2] · · Me2CO complex (8). The structures of complexes 2 and 4–8 were established by X-ray diffraction. All compounds were characterized by elemental analysis, electronic absorption spectroscopy, 1H NMR and IR spectroscopy, mass spectrometry, and cyclic voltammetry.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. R. Dilworth and S. J. Parrott, Chem. Soc. Rev., 1998, 27, 43.

    Article  CAS  Google Scholar 

  2. S. Jurisson, D. Berning, W. Jia, and D. Ma, Chem. Rev., 1993, 93, 1137.

    Article  CAS  Google Scholar 

  3. B. Johanssen and H. Spies, Top. Curr. Chem., 1996, 176, 77.

    Google Scholar 

  4. V. W.-W. Yam, C.-C. Ko, and N. Zhu, J. Am. Chem. Soc., 2004, 127, 34.

    Google Scholar 

  5. J. K. Grey, M. Triest, I. S. Butler, and C. Reber, J. Phys. Chem., A, 2001, 105, 6269.

    Article  CAS  Google Scholar 

  6. C. Savoie, C. Reber, S. Belanger, and A. L. Beauchamp, Inorg. Chem., 1995, 34, 3851.

    Article  CAS  Google Scholar 

  7. H. H. Thorp, J. Van Houten, and H. B. Gray, Inorg. Chem., 1989, 28, 889.

    Article  CAS  Google Scholar 

  8. C. Savoie and C. Reber, J. Am. Chem. Soc., 2000, 112, 844.

    Article  Google Scholar 

  9. K. P. Mareska, D. J. Rose, and J. Zubieta, Inorg. Chim. Acta, 1997, 260, 83.

    Article  Google Scholar 

  10. G. Backes-Dahmann and H. Enemark, Inorg. Chem., 1987, 26, 3960.

    Article  CAS  Google Scholar 

  11. J. J. Lock and G. Turner, Can. J. Chem., 1978, 56, 179.

    Article  CAS  Google Scholar 

  12. S. Fortin and A. L. Beauchamp, Inorg. Chim. Acta, 1998, 279, 159.

    Article  CAS  Google Scholar 

  13. L. Hansen, E. Alessio, M. Iwamoto, P. A. Marzilli, and L. G. Marzilli, Inorg. Chim. Acta, 1995, 240, 413.

    Article  CAS  Google Scholar 

  14. H. A. Hinton, H. Chen, T. A. Hamor, F. S. McQuillan, and C. J. Jones, Inorg. Chim. Acta, 1999, 285, 55.

    Article  CAS  Google Scholar 

  15. G. N. Holder and L. A. Bottomley, Inorg. Chim. Acta, 1992, 194, 133.

    Article  CAS  Google Scholar 

  16. F. E. Hahn, L. Imhof, and T. Lugger, Inorg. Chim. Acta, 1998, 269, 347.

    Article  CAS  Google Scholar 

  17. E. Alessio, E. Zangrando, E. Iengo, M. Macchi, P. A. Marzilli, and L. G. Marzilli, Inorg. Chem., 2000, 39, 294.

    Article  CAS  Google Scholar 

  18. E. Alessio, L. Hansen, M. Iwamoto, and L. G. Marzilli, J. Am. Chem. Soc., 1996, 118, 7593.

    Article  CAS  Google Scholar 

  19. L. G. Marzilli, M. Iwamoto, E. Alessio, L. Hansen, and M. Calligaris, J. Am. Chem. Soc., 1994, 116, 815.

    Article  CAS  Google Scholar 

  20. C. Pearson and A. L. Beauchamp, Inorg. Chem., 1998, 37, 1242.

    Article  CAS  Google Scholar 

  21. N. V. Pervukhina, M. N. Sokolov, N. E. Fyodorova, and V. E. Fedorov, Zh. Struct. Khim., 2001, 42, 993 [J. Struct. Chem., 2001, 42, 991 (Engl. Transl.)].

    Google Scholar 

  22. M. N. Sokolov, N. E. Fyodorova, V. E. Fedorov, A. V. Virovets, and P. Nuñez, Izv. Akad. Nauk, Ser. Khim., 2002, 804 [Russ. Chem. Bull., Int. Ed., 2002, 51, 804].

    Google Scholar 

  23. M. Sokolov, N. Fyodorova, N. Pervukhina, V. Fedorov, and D. Fenske, XXXV ICCC Abstracts, Heidelberg, Germany, 2002, 262.

  24. B. Machura, J. O. Dzięgielewski, R. Kruszynski, T. J. Bartczak, and J. Kusz, Inorg. Chim. Acta, 2004, 357, 1011.

    Article  CAS  Google Scholar 

  25. B. Machura, M. Jaworska, and R. Kruszynski, Polyhedron, 2004, 23, 1819.

    Article  CAS  Google Scholar 

  26. B. Machura, J. O. Dzięgielewski, R. Kruszynski, and T. J. Bartczak, Polyhedron, 2003, 22, 2869.

    Article  CAS  Google Scholar 

  27. B. Machura, M. Jaworska, and R. Kruszynski, Polyhedron, 2004, 23, 2005.

    Article  CAS  Google Scholar 

  28. S. Ranjan, Sh.-Y. Lin, K.-Ch. Hwang, Y. Chi, W.-L. Ching, Ch.-Sh. Lin, Y.-T. Tao, Ch.-H. Chen, Sh.-M. Peng, and G.-H. Lee, Inorg. Chem., 2003, 42, 1248.

    Article  CAS  Google Scholar 

  29. A. Paulo, J. D. G. Correia, and I. Santos, Trends. Inorg. Chem., 1998, 5, 57.

    CAS  Google Scholar 

  30. C. Pearson and A. L. Beauchamp, Acta Cryst. C, 1994, 50, 42.

    Article  Google Scholar 

  31. L. G. Marzilli, M. Iwamoto, E. Alessio, L. Hansen, and M. Calligaris, J. Am. Chem. Soc., 1994, 116, 815.

    Article  CAS  Google Scholar 

  32. A.-M. Lebuis and A. L. Beauchamp, Acta Cryst. C, 1994, 50, 882.

    Article  Google Scholar 

  33. A.-M. Lebuis and A. L. Beauchamp, Can. J. Chem., 1993, 71, 2060.

    Article  CAS  Google Scholar 

  34. S. Fortin and A. L. Beauchamp, Inorg. Chem., 2000, 39, 4886.

    Article  CAS  Google Scholar 

  35. S. Belanger and A. L. Beauchamp, Acta Cryst. C, 1999, 55, 517.

    Article  Google Scholar 

  36. A. Guest and C. J. L. Lock, Can. J. Chem., 1971, 49, 603.

    Article  Google Scholar 

  37. G. Mattistuzzi, A. B. Corradi, D. Dallari, M. Saladini, and R. Battistuzzi, Polyhedron, 1999, 18, 57.

    Article  Google Scholar 

  38. B. Machura, J. O. Dzięgielewski, R. Kruszynski, T. J. Bartczak, and J. Kusz, Inorg. Chem. Commun., 2003, 6, 1436.

    Article  CAS  Google Scholar 

  39. B. Machura, Coord. Chem. Rev., 2005, 249, 591.

    Article  CAS  Google Scholar 

  40. D. S. Bohle and E. S. Sagan, Eur. J. Inorg. Chem., 2000, 1609.

  41. H. D. Grundy and I. D. Brown, Can. J. Chem., 1970, 48, 1151.

    Article  CAS  Google Scholar 

  42. G. N. Holder and L. A. Bottomley, Inorg. Chim. Acta, 1992, 194, 133.

    Article  CAS  Google Scholar 

  43. M. S. Ram, L. M. Skeens-Jones, C. S. Johnson, X. L. Zhang, C. Stern, D. I. Yoon, D. Selmarten, and J. T. Hupp, J. Am. Chem. Soc., 1995, 117, 1411.

    Article  CAS  Google Scholar 

  44. O. Arp and W. Preetz, Z. Anorg. Allg. Chem., 1996, 622, 219.

    Article  CAS  Google Scholar 

  45. G. M. Sheldrick, SHELX-97 Release 97-2, University of Göttingen, Germany, 1998.

    Google Scholar 

  46. S. Belanger and A. L. Beauchamp, Inorg. Chem., 1997, 36, 3640.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrentieva, 630090, Novosibirsk, Russian Federation

    M. N. Sokolov, N. E. Fedorova, N. V. Pervukhina, E. V. Peresypkina, A. V. Virovets & V. E. Fedorov

  2. Institute of Inorganic Chemistry, University of Karlsruhe, Engesser str. 30.45, 76128, Karlsruhe, Germany

    N. E. Fedorova, R. Pätow & D. Fenske

Authors
  1. M. N. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. N. E. Fedorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Pervukhina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. V. Peresypkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Virovets
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. R. Pätow
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. E. Fedorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. D. Fenske
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 52–59, January, 2006.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sokolov, M.N., Fedorova, N.E., Pervukhina, N.V. et al. Rhenium(IV) and rhenium(V) complexes with 3,5-dimethylpyrazole. Russ Chem Bull 55, 53–61 (2006). https://doi.org/10.1007/s11172-006-0214-2

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-006-0214-2

Key words

Search

Navigation