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New organic metal β-(DOET)2FSO3 · H2O: Synthesis and crystal structure

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Abstract

An organic metal β-(DOET)2FSO3 · H2O based on a novel donor DOET (DOET is (1,4-dioxane-2,3-diyldithio)ethylenedithiotetrathiafulvalene) was synthesized and structurally characterized. Single crystals were prepared by electrochemical oxidation of DOET in the d.c. mode. The salt has a layered structure with the DOET1/2+ radical cation layers parallel to the ab plane. The FSO −3 anion is equiprobably disordered over two positions relative to the center of symmetry (1/2, 0, 0). The temperature behavior of conductivity is characteristic of metals in the temperature range from 293 down to 96 K; below 96 K, an increase in resistance is observed.

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Authors and Affiliations

  1. Institute for Microelectronics Technology, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. A. Bardin

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. I. Kotov, G. V. Shilov & E. B. Yagubskii

Authors
  1. A. A. Bardin
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  2. A. I. Kotov
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  3. G. V. Shilov
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  4. E. B. Yagubskii
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2387–2389, October, 2005.

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Bardin, A.A., Kotov, A.I., Shilov, G.V. et al. New organic metal β-(DOET)2FSO3 · H2O: Synthesis and crystal structure. Russ Chem Bull 54, 2463–2465 (2005). https://doi.org/10.1007/s11172-006-0139-9

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  • DOI: https://doi.org/10.1007/s11172-006-0139-9

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