Abstract
Electron ionization mass spectra of biologically active ferrocenylalkylazoles CpFeC5H4CH(R)Az (R = H, Me, Et, Pr, or Ph; AzH is pyrazole, imidazole, indazole, benzoimidazole, benzotriazole, adenine, or their derivatives) were studied. The nature of the heterocyclic fragment (its ionization energy) is the main factor determining the reactivity of these compounds under conditions of dissociative electron ionization.
Similar content being viewed by others
References
L. V. Popova, V. N. Babin, Yu. A. Belousov, Yu. S. Nekrasov, A. E. Snegireva, N. P. Borodina, G. M. Shaposhnikova, O. V. Buchenko, P. M. Raevskii, N. V. Morozova, A. I. Ilyina, and K. G. Shitkov, Appl. Organomet. Chem., 1993, 7, 85.
V. N. Babin, P. M. Raevskii, K. G. Shchitkov, L. V. Snegur, and Yu. S. Nekrasov, Ross. Khim. Zh. 1995, 39, 19 [Mendeleev Chem. J., 1995, 39, 17 (Engl. Transl.)].
L. V. Snegur, Yu. S. Nekrasov, V. V. Gumenyuk, Zh. V. Zhilina, N. B. Morozova, I. K. Sviridova, I. A. Rodina, N. S. Sergeeva, K. G. Shchitkov, and B. N. Babin, Ross. Khim. Zh., 1998, 42, 178 [Mendeleev Chem. J., 1998, 42 (Engl. Transl.)].
L. V. Snegur, V. I. Boev, Yu. S. Nekrasov, M. M. Ilyin, V. A. Davankov, Z. A. Starikova, A. I. Yanovsky, A. F. Kolomiets, and V. N. Babin, J. Organomet. Chem., 1999, 580, 26.
Yu. S. Nekrasov and D. V. Zagorevskii, Org. Mass Spectrom., 1991, 26, 733.
J. Muller, Angew. Chem., Int. Ed., 1972, 11, 653.
H. Egger, Monatsch. Chem., 1966, B97, 602.
V. V. Gumenyuk, Z. A. Starikova, Yu. S. Nekrasov, and V. N. Babin, Izv. Akad. Nauk, Ser. Khim., 2002, 1744 [Russ. Chem. Bull., Int. Ed., 2002, 51, 1894].
Yu. S. Nekrasov, D. V. Zverev, and A. I. Belokon’, Izv. Akad. Nauk, Ser. Khim., 1998, 1374 [Russ. Chem. Bull., 1998, 47, 1336 (Engl. Transl.)].
S. G. Lias, J. E. Bartmess, J. F. Liedman, J. L. Holmes, R. D. Levin, and W. G. Mallard, J. Phys. Chem. Ref. Data, 1988, 17,Suppl. No. 1.
S.-C. Chen, J. Organomet. Chem., 1980, 202, 183.
A. A. Simenel, Yu. V. Kuzmenko, E. A. Morozova, M. M. Ilyin, I. F. Gun’ko, and L. V. Snegur, J. Organomet. Chem., 2003, 688, 138.
L. V. Snegur, Dr. Sc. (Chem.) Thesis, A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow, 2002, 192 pp. (in Russian).
C. Price, M. Aslanoglu, C. J. Isaac, M. R. J. Elsegood, W. Clegg, B. R. Horrocks, and A. Holton, J. Chem. Soc., Dalton Trans., 1996, 4115.
L. V. Snegur, A. A. Simenel, Yu. S. Nekrasov, E. A. Morozova, Z. A. Starikova, S. M. Peregudova, Yu. V. Kuzmenko, V. N. Babin, L. A. Ostrovskaya, N. V. Bluchterova, and M. M. Fomina, J. Organomet. Chem., 2004, 689, 2473.
Yu. N. Sukharev and Yu. S. Nekrasov, Org. Mass Spectrom., 1976, 11, 1232.
Author information
Authors and Affiliations
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2384–2386, October, 2005.
Rights and permissions
About this article
Cite this article
Nekrasov, Y.S., Skazov, R.S., Simenel, A.A. et al. Reactivity of ferrocenylalkylazoles under conditions of dissociative ionization. Russ Chem Bull 54, 2460–2462 (2005). https://doi.org/10.1007/s11172-006-0138-x
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-006-0138-x