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A new method for modification of CN-palladacycles

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Abstract

The reaction of benzylaminate CN-palladacycle with chlorine dioxide was found to produce the 3-chlorine-substituted analog through the formal insertion of chlorine into the Pd-C bond followed by repeated ortho-palladation of the modified ligand. The structure of the resulting dimeric complex was confirmed by X-ray diffraction study of its triphenylphosphine derivative. A comparison of the 1H NMR spectra of the phosphine adducts of the starting and chlorinated complexes shows high conformational stability of the new palladacycle. Advantages of the new route to conformational stabilization of labile palladacycles are discussed.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    V. V. Dunina & Yu. K. Grishin

  2. Institute of Physiologically Active Compounds, Russian Academy of Sciences, 1 Severnyi proezd, 142432, Chernogolovka, Moscow region, Russian Federation

    O. N. Gorunova

  3. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    L. G. Kuz’mina & A. V. Churakov

  4. Institute of Chemistry, Komi Science Center, Ural Branch of the Russian Academy of Sciences, 48 ul. Pervomaiskaya, 167610, Syktyvkar, Russian Federation

    A. V. Kuchin

  5. Department of Chemistry, University of Durham, South Road, Durham, DH1 3LE, UK

    J. A. K. Howard

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  1. V. V. Dunina
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  4. L. G. Kuz’mina
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Dedicated to Academician N. S. Zefirov on the occasion of his 70th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2010–2019, September, 2005.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2010–2019, September, 2005.

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Dunina, V.V., Gorunova, O.N., Grishin, Y.K. et al. A new method for modification of CN-palladacycles. Russ Chem Bull 54, 2073–2082 (2005). https://doi.org/10.1007/s11172-006-0079-4

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  • DOI: https://doi.org/10.1007/s11172-006-0079-4

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