Abstract
The features of cumene oxidation, α-phenylisopropyl hydroperoxide (ROOH) decomposition, and free radical formation in the presence of cetyltrimethylammonium bromide (CTAB) were studied by the kinetic methods and TLC product analysis. It was found that CTAB catalyzes ROOH decomposition to free radicals. The efficiency of an initiating system CTAB—ROOH is by a factor of 2.5 higher than that of a combination CTAB with α-phenylethyl hydroperoxide. In addition, CTAB catalyzes the reactions of ROOH with α-tocopherol and 2,2′-bis[2-(p-dimethylaminophenyl)indane-1,3-dione]. The kinetic characteristics of these reactions were determined.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1802–1807, August, 2005.
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Pisarenko, L.M., Maksimova, T.V. & Kasaikina, O.T. Features of α-phenylisopropyl hydroperoxide decomposition catalyzed by cetyltrimethylammonium bromide. Russ Chem Bull 54, 1855–1861 (2005). https://doi.org/10.1007/s11172-006-0048-y
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DOI: https://doi.org/10.1007/s11172-006-0048-y