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Acceptor-type graphite intercalation compounds and new carbon materials based on them

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Abstract

The problems of synthesis and study of the physicochemical properties of graphite intercalation compounds (GIC) formed upon insertion of various molecules into the interplanar space of graphite are considered. Binary and ternary intercalation compounds with protonic acids (HNO3, CH3COOH, H3PO4, H2SO4, etc.) are described. The results of systematic research into graphite intercalation by potentiometry, calorimetry, powder X-ray diffraction, conductivity measurements, DTA, chemical analysis, and other methods are given. These results underlie elucidation of the characteristic and peculiar features of acid insertion into graphite. The physicochemical properties and practical applications of GIC and low-density carbon materials are analyzed.

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  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    N. E. Sorokina, I. V. Nikol'skaya, S. G. Ionov & V. V. Avdeev

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  1. N. E. Sorokina
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  2. I. V. Nikol'skaya
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  3. S. G. Ionov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1699–1716, August, 2005.

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Sorokina, N.E., Nikol'skaya, I.V., Ionov, S.G. et al. Acceptor-type graphite intercalation compounds and new carbon materials based on them. Russ Chem Bull 54, 1749–1767 (2005). https://doi.org/10.1007/s11172-006-0034-4

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