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New reaction pathway of dialkyl phosphorochloridites with salts of α-benzylideneaminocarboxylic acids. Direct synthesis of α-aminophosphonates from isostructural α-benzylideneaminocarboxylic acids

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Abstract

The reaction of sodium N-benzylidenevalinate with dialkyl phosphorochloridites is accompanied by decarboxylation and yields diastereomeric N-(1-dialkoxyphosphoryl-2-methylpropyl)-N-(1-dialkoxyphosphorylbenzyl)amines.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    E. V. Bayandina, E. Yu. Davydova, M. A. Abaskalova, R. Z. Musin & V. A. Al'fonsov

Authors
  1. E. V. Bayandina
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  2. E. Yu. Davydova
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  3. M. A. Abaskalova
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  4. R. Z. Musin
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  5. V. A. Al'fonsov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1449–1452, June, 2005.

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Bayandina, E.V., Davydova, E.Y., Abaskalova, M.A. et al. New reaction pathway of dialkyl phosphorochloridites with salts of α-benzylideneaminocarboxylic acids. Direct synthesis of α-aminophosphonates from isostructural α-benzylideneaminocarboxylic acids. Russ Chem Bull 54, 1492–1495 (2005). https://doi.org/10.1007/s11172-005-0433-y

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  • DOI: https://doi.org/10.1007/s11172-005-0433-y

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