Abstract
The formation of HXeCCH molecules and HXeCC⋅ radicals resulting from chemical reactions in solid xenon-acetylene systems irradiated with fast electrons was studied by low-temperature IR and EPR spectroscopies. The data obtained confirm the assignment of an absorption band with maximum at 1478 cm−1 to the H-Xe stretching vibrations in the HXeCC⋅ radical. Relativistic density functional calculations with inclusion of anharmonic corrections permit a quantitative description of the vibrational spectra of xenon-containing molecules and radicals. Preliminary experimental and computational data on the magnetic resonance parameters of the HXeCC⋅ radical were obtained. This radical is characterized by large hyperfine coupling constants with magnetic nuclei of the xenon isotopes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Pettersson, J. Lundell, and M. Rasanen, J. Chem. Phys., 1995, 102, 6423.
M. Pettersson, J. Lundell, and M. Rasanen, J. Chem. Phys., 1995, 103, 205.
V. I. Feldman and F. F. Sukhov, Chem. Phys. Lett., 1996, 255, 425.
V. I. Feldman, F. F. Sukhov, and A. Yu. Orlov, Chem. Phys. Lett., 1997, 280, 507.
M. Pettersson, J. Nieminen, L. Khriachtchev, and M. Rasanen, J. Chem. Phys., 1997, 107, 8423.
M. Pettersson, J. Lundell, and M. Rasanen, Eur. J. Inorg. Chem., 1999, 729.
L. Khriachtchev, M. Pettersson, N. Runeberg, J. Lundell, and M. Rasanen, Nature (London), 2000, 406, 874.
J. Lundell, A. Cohen, and B. Gerber, J. Phys. Chem. A, 2002, 106, 11950.
V. I. Feldman, F. F. Sukhov, A. Yu. Orlov, and I. V. Tyulpina, J. Am. Chem. Soc., 2003, 125, 4698.
L. Khriachtchev, H. Tanskanen, J. Lundell, M. Pettersson, H. Kiljunen, and M. Rasanen, J. Am. Chem. Soc., 2003, 125, 4696.
L. Khriachtchev, H. Tanskanen, A. Cohen, R. B. Gerber, J. Lundell, M. Pettersson, H. Kiljunen, and M. Rasanen, J. Am. Chem. Soc., 2003, 125, 6876.
H. Tanskanen, L. Khriachtchev, J. Lundell, and M. Rasanen, J. Chem. Phys., 2004, 121, 8291.
F. F. Sukhov, D.Sc. (Chem.) Thesis, L. Ya. Karpov Institute of Physical Chemistry, Moscow, 1988 (in Russian).
V. I. Feldman, Acta Chem. Scand., 1997, 51, 181.
V. I. Feldman, F. F. Sukhov, N. A. Slovokhotova, and V. P. Bazov, Radiat. Phys. Chem., 1996, 48, 261.
V. I. Feldman, Radiat. Phys. Chem., 1999, 55, 565.
J. P. Perdew, K. Burke, and M. Ernzerhof, Phys. Rev. Lett., 1996, 77, 3865.
D. N. Laikov, Abstr. DFT200 — Satellite Symp. 10th Int. Congr. Quantum Chem. (June 11–14, 2000), Menton (France), 2000, 43.
D. N. Laikov, Chem. Phys. Lett., 1997, 281, 151.
N. I. Bagdanskis, M. O. Bulanin, and Yu. V. Fadeev, Opt. Spektrosk., 1970, 29, 667 [Opt. Spectrosc., 1970, 29 (Engl. Transl.)].
G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules, New York, 1945.
H. Kunttu, J. Seetula, M. Rasanen, and A. Apkarian, J. Chem. Phys., 1992, 96, 5630.
G. Maier and C. Lautz, Eur. J. Org. Chem., 1998, 769.
L. Andrews, G. P. Kushto, M. Zhou, S. P. Wilson, and P. F. Souter, J. Chem. Phys., 1999, 110, 4457.
L. Khriachtchev, H. Tanskanen, M. Pettersson, M. Rasanen, V. Feldman, F. Sukhov, A. Orlov, and A. F. Shestakov, J. Chem. Phys., 2002, 116, 5708.
R. A. Shepherd, T. J. Doyle, and W. R. H. Graham, J. Chem. Phys., 1988, 89, 2738.
L. Khriachtchev, H. Tanskanen, J. Lundell, M. Pettersson, H. Kiljunen, and M. Rasanen, J. Am. Chem. Soc., 2003, 125, 1454.
Author information
Authors and Affiliations
Additional information
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1415–1423, June, 2005.
Rights and permissions
About this article
Cite this article
Feldman, V.I., Sukhov, F.F., Orlov, A.Y. et al. Chemical reactions in the xenon-acetylene systems irradiated with fast electrons at 16 K: formation of xenon-containing molecules and radicals. Russ Chem Bull 54, 1458–1466 (2005). https://doi.org/10.1007/s11172-005-0427-9
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/s11172-005-0427-9