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Electrochemical approaches to the generation of (arylphosphinidene)pentacarbonyltungsten

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Abstract

The possibility of formation of arylphosphinidene complexes with tungsten pentacarbonyl ArP=W(CO)5 upon the nucleophilic substitution of the chlorine atoms in aryldichlorophosphines ArPCl2 by the electrochemically generated [W(CO)5]2− anion is demonstrated.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    Yu. G. Budnikova, T. V. Gryaznova, A. R. Yagfarov & O. G. Sinyashin

Authors
  1. Yu. G. Budnikova
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  2. T. V. Gryaznova
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  3. A. R. Yagfarov
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  4. O. G. Sinyashin
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1356–1359, June, 2005.

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Budnikova, Y.G., Gryaznova, T.V., Yagfarov, A.R. et al. Electrochemical approaches to the generation of (arylphosphinidene)pentacarbonyltungsten. Russ Chem Bull 54, 1398–1401 (2005). https://doi.org/10.1007/s11172-005-0417-y

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  • DOI: https://doi.org/10.1007/s11172-005-0417-y

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