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Construction of Fe3O4@SiO2-Amine-DAB/Py-CuCl2 nanocomposite as an efficient and reusable nanocatalyst for the synthesis of 2,3,5-triaryl furans and diaryl sulfoxides

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Abstract

Herin, we demonstrate the synthesis and catalytic efficacy of Fe3O4@SiO2-Amine-DAB/Py-CuCl2 nanocomposite as a novel catalyst in synthesizing various 2,3,5-triaryl furans via oxidative cyclization of aryl ketones with styrenes and oxidation of sulfides to sulfoxides under eco-friendly conditions. Our catalytic system accommodates a broad substrate scope, encompassing aryl ketones, styrenes, and aryl sulfides with both withdrawing and donating groups on the ring, yielding target products with high yields. Additionally, the catalyst exhibits notable reusability, maintaining stable efficiency over seven runs, as confirmed by VSM, TEM, and ICP-OES analyses, which validate the structural integrity of Fe3O4@SiO2-Amine-DAB/Py-CuCl2 even after eight recovery cycles. The developed Fe3O4@SiO2-Amine-DAB/Py-CuCl2 nanocomposite catalyst, demonstrating its efficiency and reusability in synthesizing 2,3,5-triaryl furans and diaryl sulfoxides under environmentally friendly conditions, which contributes significantly to the advancement of green catalysis methodologies.

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Acknowledgements

The authors are thankful to the Researchers Supporting Project (RSP2024R113), King Saud University, Riyadh, Saudi Arabia.                                                                      

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Researchers Supporting Project (RSP2024R113), King Saud University, Riyadh, Saudi Arabia.

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Authors and Affiliations

  1. Department of Chemical and Petroleum Refinery Engineering College of Oil and Gas Engineering, Basrah University for Oil and Gas, Basrah, Iraq

    Firas H. Albadran

  2. Basrah University for Oil and Gas, Basrah, Iraq

    Nabeel K. Abbood

  3. Petroleum Engineering Department, Basrah University College of Science and Engineering, Basrah, Iraq

    Ibtisam Kamal

  4. Department of Chemistry, College of Science, King Saud University, Riyadh, 11451, Saudi Arabia

    Manawwer Alam

  5. Department of Chemistry, Shanghai University, Shanghai, China

    Li-Yuan Chang

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  1. Firas H. Albadran
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Contributions

Firas H. Albadran: Performing Experimental works. Nabeel K. Abbood: Performing Experimental works. Ibtisam Kamal: Taking analyzes. Manawwer Alam: Helpping in experimental works and analyzes. Li-Yuan Chang: Manager project, Witting the paper.

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Albadran, F.H., Abbood, N.K., Kamal, I. et al. Construction of Fe3O4@SiO2-Amine-DAB/Py-CuCl2 nanocomposite as an efficient and reusable nanocatalyst for the synthesis of 2,3,5-triaryl furans and diaryl sulfoxides. Res Chem Intermed (2024). https://doi.org/10.1007/s11164-024-05287-5

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