Abstract
The oxidation of different phenols, viz., phenol, 3-methylphenol, 4-methylphenol, 4-tert-butylphenol, 2-cyclohexylphenol, 2,6-di-tert-butyl-4-methylphenol, and 2,4-dichlorophenol, with chlorine dioxide in acetonitrile was studied spectrophotometrically. The reaction rate is described by a second-order equation w = k[PhOH]· [ClO2]. The rate constants were measured and activation parameters of oxidation were determined in a temperature interval of 10–60°C. A dependence of the reaction rate constant on the phenol structure was found. The oxidation products were identified, and their yields were established.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2184–2187, October, 2004.
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Ganiev, I.M., Ganieva, E.S. & Kabal’nova, N.N. Oxidation of phenols with chlorine dioxide. Russ Chem Bull 53, 2281–2284 (2004). https://doi.org/10.1007/s11172-005-0114-x
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DOI: https://doi.org/10.1007/s11172-005-0114-x