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Effect of cationic surfactants on limonene oxidation

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Abstract

Kinetic regularities of free radical formation during limonene oxidation with molecular oxygen in a chlorobenzene solution at 60 °C were studied by the inhibitor method under autooxidation conditions and with additives of surfactants (cetyltrimethylammonium chloride and bromide) using dimer 2,2′-bis[2-(p-dimethylaminophenyl)indane-1,3-dione] and α-tocopherol as acceptors of radicals. In the presence of the surfactants, the rates of radical generation and oxidation increase sharply. The catalytic activity of cetyltrimethylammonium chloride is much higher than that of the corresponding bromide.

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References

  1. K. Gollnick and G. O. Schenck, Pure Appl. Chem., 1964, 9, 507.

    CAS  Google Scholar 

  2. G. M. Kuznetsova, T. V. Lobanova, I. F. Rusina, and O. T. Kasaikina, Izv. Akad. Nauk, Ser. Khim., 1996, 1676 [Russ. Chem. Bull., 1996, 45, 1586 (Engl. Transl.)].

    Google Scholar 

  3. G. M. Kuznetsova, Z. S. Kartasheva, and O. T. Kasaikina, Izv. Akad. Nauk, Ser. Khim., 1996, 1682 [Russ. Chem. Bull., 1996, 45, 1592 (Engl. Transl.)].

    Google Scholar 

  4. G. O. Schenck, K. Gollnick, G. Buchwald, S. Schroeter, and G. Ohloff, Ann. Chem., 1964, 674, 93.

    CAS  Google Scholar 

  5. N. M. Emanuel’, E. T. Denisov, and Z. K. Maizus, Tsepnye reaktsii okisleniya uglevodorodov v zhidkoi faze [Chain Reactions of Hydrocarbon Oxidation in the Liquid Phase], Nauka, Moscow, 1965, 375 (in Russian).

    Google Scholar 

  6. T. V. Sirota and O. T. Kasaikina, Neftekhimiya, 1994, 34, No.5, 467 [Petroleum Chemistry, 1994, 34 (Engl. Transl.)].

    CAS  Google Scholar 

  7. T. V. Sirota, N. M. Evteeva, and O. T. Kasaikina, Neftekhimiya, 1996, 36, No.2, 169 [Petroleum Chemistry, 1996, 36 (Engl. Transl.)].

    CAS  Google Scholar 

  8. Z. S. Kartasheva, T. V. Maksimova, E. V. Koverzanova, and O. T. Kasaikina, Neftekhimiya, 1997, 37, No.2, 153 [Petroleum Chemistry, 1997, 37 (Engl. Transl.)].

    CAS  Google Scholar 

  9. Z. S. Kartasheva, T. V. Maksimova, T. V. Sirota, E. V. Koverzanova, and O. T. Kasaikina, Neftekhimiya, 1997, 37, No.3, 249 [Petroleum Chemistry, 1997, 37 (Engl. Transl.)].

    CAS  Google Scholar 

  10. L. J. Csanyi and K. Jaky, J. Mol. Catal. A: Chem., 1997, 120, 125.

    Article  CAS  Google Scholar 

  11. O. T. Kasaikina, V. D. Kortenska, Z. S. Kartasheva, G. M. Kuznetsova, T. V. Maximova, T. V. Sirota, and N. V. Yanishlieva, Colloid Surf. A: Physicochem. Eng. Asp., 1999, 149, 29.

    Article  CAS  Google Scholar 

  12. V. G. Kondratovich, V. D. Kortenska, Z. S. Kartasheva, N. V. Yanishlieva, I. R. Totzeva, M. I. Boneva, and O. T. Kasaikina, in Peroxides at the Beginning of the Third Millennium. Synthesis, Properties, Application, Eds V. A. Antonovsky, O. T. Kasaikina, and G. E. Zaikov, Nova Science Publ., Inc., New York, 2004, 261.

    Google Scholar 

  13. W. B. Hugo, in Surface-Active Agents in Microbiology, S. C. I. Monograph 19, Soc. Chem. Ind., London, 1965, 67.

    Google Scholar 

  14. M. Harustik, M. Hronec, and J. Ilavki, React. Kinet. Catal. Lett., 1988, 37, 215.

    Google Scholar 

  15. M. Harustik, M. Hronec, and J. Ilavki, J. Mol. Catal., 1988, 48, 335.

    Article  Google Scholar 

  16. K. Ohkubo and T. Yamabe, Bull. Jpn Pet. Inst., 1970, 12, 130.

    CAS  Google Scholar 

  17. K. Ohkubo and H. Kanaeda, Bull. Jpn Pet. Inst., 1971, 13, 177.

    CAS  Google Scholar 

  18. K. Ohkubo and K. Yoshinaga, Bull. Jpn Pet. Inst., 1977, 19, 73.

    CAS  Google Scholar 

  19. L. M. Pisarenko and O. T. Kasaikina, Izv. Akad. Nauk, Ser. Khim., 2002, 419 [Russ. Chem. Bull., Int. Ed., 2002, 51, 449].

  20. L. M. Pisarenko, Z. S. Kartasheva, T. V. Maksimova, and O. T. Kasaikina, Izv. Akad. Nauk, Ser. Khim., 2003, 1419 [Russ. Chem. Bull., Int. End., 2003, 52, 1500].

    Google Scholar 

  21. Organic Solvents. Physical Properties and Method of Purification, Ed. A. Weissberger, Intersci. Publ., New York—London, 1955.

    Google Scholar 

  22. D. Gal and N. M. Emanuel, Modelling of Oxidation Processes, Prototype: The Oxidation of Ethylbenzene, Akademiai Kiado, Budapest, 1986.

    Google Scholar 

  23. E. T. Denisov, Izv. Akad. Nauk SSSR, Ser. Khim., 1967, 1608 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1967, 16 (Engl. Transl.)].

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Authors and Affiliations

  1. N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation

    L. M. Pisarenko, V. G. Kondratovich & O. T. Kasaikina

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  1. L. M. Pisarenko
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  2. V. G. Kondratovich
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  3. O. T. Kasaikina
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2110–2113, October, 2004.

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Pisarenko, L.M., Kondratovich, V.G. & Kasaikina, O.T. Effect of cationic surfactants on limonene oxidation. Russ Chem Bull 53, 2205–2208 (2004). https://doi.org/10.1007/s11172-005-0100-3

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  • DOI: https://doi.org/10.1007/s11172-005-0100-3

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