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Solid-state chlorodecarboxylation of mono- and dicarboxylic acids with the Pb(OAc)4-MCl system

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Abstract

Solid state reactions of acids RCOOH (R = n-C7H15, BuC(Et)H, n-C9H19, PhCH2, PhCH2CH2, H2C=CH(CH2)8, or MeOOC(CH2)3) with Pb(OAc)4 combined with KCl, NaCl, CdCl2, or NH4Cl in the absence of a solvent and without mechanical activation afford chlorohydrocarbons RCl. The corresponding reactions of acids HOOC(CH2)nCOOH (n = 3–6) give dichloroalkanes Cl(CH2)nCl and γ-butyrolactone (n = 3).

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    G. I. Nikishin, L. L. Sokova, A. O. Chizhov & N. I. Kapustina

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. D. Makhaev

Authors
  1. G. I. Nikishin
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  2. L. L. Sokova
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  3. A. O. Chizhov
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  4. V. D. Makhaev
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  5. N. I. Kapustina
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2105–2109, October, 2004.

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Nikishin, G.I., Sokova, L.L., Chizhov, A.O. et al. Solid-state chlorodecarboxylation of mono- and dicarboxylic acids with the Pb(OAc)4-MCl system. Russ Chem Bull 53, 2200–2204 (2004). https://doi.org/10.1007/s11172-005-0099-5

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  • DOI: https://doi.org/10.1007/s11172-005-0099-5

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