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New cyano-bridged complexes based on tetrahedral rhenium chalcocyanide clusters, Cu2+ cations, and polydentate amines

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Abstract

Three new cyano-bridged compounds, viz., [{Cu(en)}{Cu(NH3)(en)}Re4Se4(CN)12]·{5H2O (1), [{Cu(dien)}2Re4Te4(CN)12]·9H2O (2), and [{Cu(trien)}2Re4Se4(CN)12]··5H2O (3), were synthesized by the reactions of the tetrahedral rhenium chalcocyanide cluster complexes K4[Re4Q4(CN)12] ((Q = Se or Te) with copper(II) cations in aqueous solutions containing ethylenediamine (en), diethylenetriamine (dien), or triethylenetetraamine (trien), respectively. Complex 1 has a ladder-tubular-like polymeric structure, in which two infinite chains are linked to each other by Re-CN-Cu bridges, compound 2 has a polymeric chain structure, and compound 3 has a molecular structure. The structures of all complexes were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, 3 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    Yu. V. Mironov, O. A. Efremova, S. F. Solodovnikov, N. G. Naumov & V. E. Fedorov

  2. Institute of Analytical Chemistry, Ruhr-University Bochum, D 44780, Bochum, Germany

    Yu. V. Mironov & W. S. Sheldrick

  3. Laboratory of Solid State and Inorganic Molecular Chemistry, Institute of Chemistry of Rennes, UMR 6511 CNRS University of Rennes 1, avenue du General Leclerc, 35042, Rennes, Cedex, France

    A. Perrin

Authors
  1. Yu. V. Mironov
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  2. O. A. Efremova
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  3. S. F. Solodovnikov
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  4. N. G. Naumov
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  5. W. S. Sheldrick
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  6. A. Perrin
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  7. V. E. Fedorov
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2040–2044, October, 2004.

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Mironov, Y.V., Efremova, O.A., Solodovnikov, S.F. et al. New cyano-bridged complexes based on tetrahedral rhenium chalcocyanide clusters, Cu2+ cations, and polydentate amines. Russ Chem Bull 53, 2129–2134 (2004). https://doi.org/10.1007/s11172-005-0085-y

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  • DOI: https://doi.org/10.1007/s11172-005-0085-y

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