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Acid-base and complexation properties of gem-diphosphonic and gem-diphosphinic acids in aqueous solutions and micellar media of surfactants

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Russian Chemical Bulletin Aims and scope

Abstract

Acid-base and complexation properties of gem-disubstituted phosphorus acids, viz., methylenediphosphonic, 1-hydroxyethylidene-1,1-diphosphonic, P,P′-diphenylmethylene-diphosphinic, and P, P′-diphenyl-1-hydroxyethylidene-1, 1-diphosphinic acids, were studied in aqueous solutions and in the presence of biomimetics (micelles of ionic surfactants). The dissociation constants of the acids and stability constants of complexes with magnesium(II) and copper(II) ions were determined in aqueous solutions and microheterogeneous media containing sodium dodecyl sulfate, cetylpyridinium chloride, or cetylpyridinium nitrate (ionic strength 0.1 mol L−1, temperature 25°C).

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Authors and Affiliations

  1. Department of Chemistry, V. N. Karazin Kharkov National University, 4 pl. Svobody, 61077, Kharkov, Ukraine

    L. P. Loginova & I. V. Levin

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. G. Matveeva, S. A. Pisareva & E. E. Nifant’ev

Authors
  1. L. P. Loginova
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  2. I. V. Levin
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  3. A. G. Matveeva
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  4. S. A. Pisareva
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  5. E. E. Nifant’ev
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1919–1925, September, 2004.

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Loginova, L.P., Levin, I.V., Matveeva, A.G. et al. Acid-base and complexation properties of gem-diphosphonic and gem-diphosphinic acids in aqueous solutions and micellar media of surfactants. Russ Chem Bull 53, 2000–2007 (2004). https://doi.org/10.1007/s11172-005-0062-5

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  • DOI: https://doi.org/10.1007/s11172-005-0062-5

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