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Synthesis and characterization of complexes η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 and μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2

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Abstract

The complex η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 was synthesized by the reaction of η5-Cp(CO)2Fe-η1,η5-C5H4Mn(CO)3 with BunLi (THF, −78 °C) and then with anhydrous CuCl2. The complex μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2 was prepared by the reaction of η5-IC5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3 with Me3SnC≡CSnMe3 (2:1) in the presence of Pd(MeCN)2Cl2.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    T. Yu. Orlova, Yu. S. Nekrasov, P. V. Petrovskii & M. G. Ezernitskaya

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  1. T. Yu. Orlova
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  2. Yu. S. Nekrasov
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  3. P. V. Petrovskii
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  4. M. G. Ezernitskaya
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1860–1863, September, 2004.

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Orlova, T.Y., Nekrasov, Y.S., Petrovskii, P.V. et al. Synthesis and characterization of complexes η5,η5-(CO)3Mn(C5H4-C5H4)(CO)2Fe-η1,η5-C5H4Mn(CO)3 and μ-(C≡C)[C5H4(CO)2Fe-η1,η5-C5H4Mn(CO)3]2 . Russ Chem Bull 53, 1938–1941 (2004). https://doi.org/10.1007/s11172-005-0052-7

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  • DOI: https://doi.org/10.1007/s11172-005-0052-7

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