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Cellulose-based surface-modified heterogeneously feasible novel solid acid catalyst to access bioactive heterocycles

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Abstract

Surface-modified cellulose-based heterogeneously active catalyst was prepared by covalent anchoring of chlorosulphonic acid on amino-functionalized cellulose (SA@Cell-AEPC). The structure of synthesized catalyst was confirmed by analytical methods such as FT-IR, FE-SEM, EDX, TGA, XRD, TEM and CP/MAS 13C-NMR spectroscopy. The catalytic effect was evaluated for the formation of oxygen and nitrogen heterocycles. Reusability, shorter reaction time, high conversion, wide substrate scope, easy work-up procedure are noteworthy measures of this synthetic route.

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Acknowledgements

SSK is gratefully acknowledged to the Principal, Karmaveer Bhaurao Patil Mahavidyalaya (Autonomous), Pandharpur, Solapur for providing the financial assistance under RUSA Scheme [RUSA/MRP/F.No.1/004/20-21, Dated: 5th September 2020]. Author is also thankful to the Head, Sophisticated Analytical Instrument Facility, IIT Bombay and Scientific Instrumentation Center, PAH, Solapur University, Solapur for providing spectral facilities.

Funding

This work was financially supported by the Principal, Karmaveer Bhaurao Patil Mahavidyalaya (Autonomous), Pandharpur, Solapur, Maharashtra, India under RUSA Scheme [RUSA/MRP/F.No.1/004/20-21, Dated: 5th September 2020].

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Authors and Affiliations

  1. Department of Chemistry, Karmaveer Bhaurao Patil Mahavidyalaya Pandharpur (Autonomous), Solapur, Maharashtra, India

    Shrikrishna Karhale & Ankush Kadam

  2. Department of Chemistry, R. B. Narayanrao Borawake College, Shrirampur (Autonomous), Ahmednagar, Maharashtra, India

    Shrikrishna Karhale

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  1. Shrikrishna Karhale
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Shrikrishna Karhale: Data curation, Formal analysis. Project administration, Writing main manuscript and Supervision. Ankush Kadam: Conceptualization, Methodology, prepared figures and Investigation. Both authors read and approved the final manuscript.

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Correspondence to Shrikrishna Karhale.

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Karhale, S., Kadam, A. Cellulose-based surface-modified heterogeneously feasible novel solid acid catalyst to access bioactive heterocycles. Res Chem Intermed 50, 31–48 (2024). https://doi.org/10.1007/s11164-023-05171-8

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