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Cooperative rate amplification by binary surfactant (CPC/TX-100) nano-aggregates on the diperiodatocuprate(III) (DPC) oxidation of 2-butanol in aqueous medium

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Abstract

The present research work is concerned with the systematic account of the catalytic behaviour of binary surfactant solutions during the oxidation of 2-butanol by the diperiodatocuprate(III) copper(III)–periodate complex (DPC) in an aqueous solvent. The work primarily deals with the kinetics of the mixed micelle diperiodatocuprate(III) copper(III)–periodate complex (DPC)-catalysed oxidation of 2-butanol by maintaining pseudo-first-order reaction conditions. The cetylpyridinium chloride (CPC)/Triton X-100 (TX-100) mixed micelle serves as a nano-reactor for the oxidation reaction offering a micro-heterogeneous system in an aqueous media. A strong and pronounced catalytic effect has been exhibited by a mixture of CPC and TX-100 surfactants in 1:7 molar ratio compared to any of the single surfactant. The binary surfactant system cooperatively accelerated the oxidation rate of 2-butanol by reducing the reaction completion time up to 40 times. The cetyltrimethylammonium bromide (CTAB) micelle in the reaction system substantially decreased the oxidation rate compared to the reaction in aqueous media only. Proton NMR spectra are conducted to characterize the oxidation product 2-butanone. NMR data precisely correlate the interaction behaviour of CPC and TX-100 in association with the formation of mixed micellar aggregates in the reaction system. The calculated kinetic parameters such as rate constant (kobs), half-life (t1/2) and effective rate constant (keff) values for the oxidation of 2-butanol by DPC in binary surfactant system are correlated with micellar pseudo-phase model and proton NMR analysis of mixed micelles. The blended micellar catalyst has been recovered and recycled for the next reaction as soon as the oxidation of 2-butanol is finished up.

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Authors and Affiliations

  1. Department of Chemistry, The University of Burdwan, Golapbag, Burdwan, West Bengal, 713104, India

    Budhadeb Chowdhury, Aniruddha Ghosh, Sk Mehebub Rahaman & Bidyut Saha

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  1. Budhadeb Chowdhury
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  2. Aniruddha Ghosh
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  3. Sk Mehebub Rahaman
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  4. Bidyut Saha
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BC and SMR conducted the main research experiments and wrote the draft of the manuscript. AG and BC analysed the data. BC and AG revised the manuscript. BS supervised the manuscript.

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Correspondence to Bidyut Saha.

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Chowdhury, B., Ghosh, A., Rahaman, S.M. et al. Cooperative rate amplification by binary surfactant (CPC/TX-100) nano-aggregates on the diperiodatocuprate(III) (DPC) oxidation of 2-butanol in aqueous medium. Res Chem Intermed 49, 4041–4063 (2023). https://doi.org/10.1007/s11164-023-05069-5

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