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Synthesis of benzo[b]pyran and pyrano[2,3-d]pyrimidine derivatives using a new superparamagnetic nanocatalyst Fe3O4@gly@Furfural@Co(NO3)2

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Abstract

In this work, the surface of Fe3O4 nanoparticles was functionalized with the glycine, furfural, and cobalt (II) nitrate hexahydrate to synthesize a novel support nanocatalyst (Fe3O4@gly@Furfural@Co(NO3)2). The characteristics of the nanocatalyst were confirmed by various techniques, such as energy-dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectrometer, EDX mapping, scanning electron microscopy, X-ray diffraction, thermal gravimetric/derivative thermal gravimetric, vibrating sample magnetometer, and TEM. Finally, the performance of the nanocatalyst was investigated for the one-pot multicomponent synthesis of benzo[b]pyran and pyrano[2,3-d] pyrimidine derivatives. The good–excellent yield of the products was achieved in a green solvent under mild conditions at short reaction time. In addition, the green heterogeneous catalyst has features, such as environmental friendliness, easy separation from the reaction mixture by an external magnet, high catalytic activity, and reusability up to 6 stages without significant reduction of its catalytic activity.

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Acknowledgements

The authors gratefully appreciate the financial support from the Research Council of University of Sistan and Baluchestan.

Funding

Funding was provided by University of Sistan and Baluchestan.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Sistan and Baluchestan, P.O. Box 98135-674, Zahedan, Iran

    Raheleh Keshani, Nourallah Hazeri, Homayoun Faroughi Niya & Maryam Fatahpour

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  1. Raheleh Keshani
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  2. Nourallah Hazeri
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  3. Homayoun Faroughi Niya
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  4. Maryam Fatahpour
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Contributions

RK (the PhD. student) performed the practical laboratory work and wrote the manuscript. NH (Supervisor, PhD) designed the research project. HFN (Advisor, PhD) helped Miss RK to do her PhD. research project in optimized conditions. MF (Advisor, PhD) helped Miss RK with the formal analysis, writing, and editing of her manuscript.

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Correspondence to Nourallah Hazeri.

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Keshani, R., Hazeri, N., Faroughi Niya, H. et al. Synthesis of benzo[b]pyran and pyrano[2,3-d]pyrimidine derivatives using a new superparamagnetic nanocatalyst Fe3O4@gly@Furfural@Co(NO3)2. Res Chem Intermed 49, 3461–3479 (2023). https://doi.org/10.1007/s11164-023-05044-0

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