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A V(O)-Schiff-base complex on MCM-41 as an efficient, reusable, and chemoselective nanocatalyst for the oxidative coupling of thiols and oxidation of sulfides

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Abstract

The chemoselective oxidative coupling of thiols to disulfides and oxidation of sulfides to corresponding sulfoxides are significant procedures in organic chemistry. Therefore, we have investigated 5-nitro-salicylaldehyde Schiff-base complex of vanadium oxide on MCM-41 (V(O)-5NSA-MCM-41) as a stable, efficient, reusable, and chemoselective nanocatalyst for the synthesis of disulfide and sulfoxide derivatives using hydrogen peroxide (H2O2) as biocompatibility, inexpensive, and available oxidant. V(O)-5NSA-MCM-41 was characterized using various techniques such as SEM, EDS, WDX, XRD, TEM, TGA, BET, and FTIR. This catalyst can be recovered and reused several times without significant loss in catalytic activity. In addition, the recovered catalyst was characterized with several techniques, which are showing an excellent agreement with fresh catalyst before reusing. A comparison of reused and un-reused catalysts confirmed the heterogeneous nature of this catalyst.

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Acknowledgements

Authors thank the research facilities of Ilam University, Ilam, Iran, for financial support of this research project. Also, financial support for this work by the research affairs of Islamic Azad University, Qeshm Branch, Qeshm, Iran is gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry, Qeshm Branch, Islamic Azad University, Qeshm, Iran

    Arida Jabbari

  2. Department of Chemistry, Ilam University, P.O. Box 69315516, Ilam, Iran

    Mohsen Nikoorazm & Parisa Moradi

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  1. Arida Jabbari
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  2. Mohsen Nikoorazm
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  3. Parisa Moradi
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AJ contributed to methodology and investigation. MN contributed to supervision. PM contributed to writing—original draft, writing—review and editing.

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Correspondence to Arida Jabbari or Mohsen Nikoorazm.

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Jabbari, A., Nikoorazm, M. & Moradi, P. A V(O)-Schiff-base complex on MCM-41 as an efficient, reusable, and chemoselective nanocatalyst for the oxidative coupling of thiols and oxidation of sulfides. Res Chem Intermed 49, 1485–1505 (2023). https://doi.org/10.1007/s11164-023-04977-w

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