Skip to main content
SpringerLink
Log in

RSM optimization of biodiesel production by a novel composite of Fe(ΙΙΙ)-based MOF and phosphomolybdic acid

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

The synthesis of MIL-53 samples and encapsulation process of phosphomolybdic acid were implemented using ultrasound at ambient temperature and atmospheric pressure. Analysis of the results showed that H3PMo salts have strong electrostatic interactions with the iron (III) lattice, which plays an important role in reducing leaching from the compound. Characterization of newly synthesized nanocomposite was carried out using various techniques such as XRD, FT-IR, SEM, EDS, BET, ICP and NH3-TPD. The catalytic activity of the prepared nanocomposites, PMA@MIL-53(Fe), was tested through the esterification reaction of oleic acid with methanol under ultrasonic irradiation. Biodiesel production process using certain molar ratio of oleic acid/methanol, PMA@MIL-53(Fe) as catalyst (50–200 mg) containing different amounts of PMA (0–40%), at different reaction times (5–25 min) and ambient temperature under ultrasound conditions was optimized using CCD tab of Design Expert software. The results indicated that the synthesized composites show excellent catalytic activity.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

References

  1. M.A. Mujtaba, M.C. Haeng, H.H. Masjuki, M.A. Masjuki, H.C. Ong, M. Gul, M.H. Harith, M.N.A.M. Yusoff, Energy. Rep. 6, 40 (2020)

    Article  Google Scholar 

  2. F. Ma, M.A. Hanna, Bioresour. Technol. 70, 1 (1999)

    Article  CAS  Google Scholar 

  3. M.Y. Koh, T.I.M. Ghazi, Renew. Sust. Energy. Rev. 15, 2240 (2011)

    Article  CAS  Google Scholar 

  4. S. Dharma, H.C. Ong, H. Masjuki, A. Sebayang, A. Silitonga, Energy. Convers. Manage. 128, 66 (2016)

    Article  CAS  Google Scholar 

  5. S.T. Hong, J.W. Kim, W.H. Jang, J.S. Lim, H.S. Park, K.P. Yoo, C. Apfel, Res. Chem. Intermed. 35, 197 (2009)

    Article  CAS  Google Scholar 

  6. S. Abbasi, U.M. Diwekar, Clean Technol. Environ. Policy 16, 79 (2014)

    Google Scholar 

  7. S. Mohapatra, P. Das, D. Swain, S. Satapathy, S.R. Sahu, Int. J. Curr. Eng. Technol. 6, 100 (2016)

    Google Scholar 

  8. A.P. Vyas, J.L. Verma, N. Subrahmanyam, Fuel 89, 1 (2010)

    Article  CAS  Google Scholar 

  9. A. Nikseresht, A. Daniyali, M. Ali-Mohammadi, A. Afzalinia, A. Mirzaie, Ultrason. Sonochem. 37, 203 (2017)

    Article  CAS  PubMed  Google Scholar 

  10. A. Afzalinia, A. Mirzaie, A. Nikseresht, T. Musabeygi, Ultrason. Sonochem. 34, 713 (2017)

    Article  CAS  PubMed  Google Scholar 

  11. S.X. Tan, S. Lim, H.C. Ong, Y.L. Pang, Fuel 235, 886 (2019)

    Article  CAS  Google Scholar 

  12. K. Ramachandran, T. Suganya, N.N. Gandhi, S. Renganathan, Renew. Sust. Energy. Rev. 22, 410 (2013)

    Article  CAS  Google Scholar 

  13. H. Yang, Z. Xiao, Y. Qu, T. Chen, Y. Chen, G. Wang, Res. Chem. Intermed. 44, 799 (2018)

    Article  CAS  Google Scholar 

  14. Y. Zhang, S. Wang, Z. Xiao, T. Chen, G. Wang, Res. Chem. Intermed. 42, 7213 (2016)

    Article  CAS  Google Scholar 

  15. W. Xie, H. Wang, J. Ind. Eng. Chem. 87, 162 (2020)

    Article  CAS  Google Scholar 

  16. W. Xie, C. Gao, J. Li, Renew. Energy 168, 927 (2021)

    Article  CAS  Google Scholar 

  17. W. Xie, F. Wan, Fuel 220, 248 (2018)

    Article  CAS  Google Scholar 

  18. W. Xie, F. Wan, Chem. Eng. J. 365, 40 (2019)

    Article  CAS  Google Scholar 

  19. H. Liu, Q. Peng, J. Ren, B. Shi, Y. Wang, J. Iran. Chem. Soc. 18, 2649 (2021)

    Article  CAS  Google Scholar 

  20. G.L. Maddikeri, A.B. Pandit, P.R. Gogate, Ind. Eng. Chem. Res. 51, 14610 (2012)

    Article  CAS  Google Scholar 

  21. M. Sánchez-Sánchez, N. Getachew, K. Díaz, M. Díaz-García, Y. Chebude, I. Díaz, Green Chem. 17, 1500 (2015)

    Article  CAS  Google Scholar 

  22. J. Pang, F. Jiang, M. Wu, C. Liu, K. Su, W. Lu, D. Yuan, M. Hong, Nat. Commun. 6, 7575 (2015)

    Article  PubMed  Google Scholar 

  23. Y. Peng, V. Krungleviciute, I. Eryazici, J.T. Hupp, O.K. Farha, T. Yildirim, J. Am. Chem. Soc. 135, 11887 (2013)

    Article  CAS  PubMed  Google Scholar 

  24. P. Horcajada, C. Serre, M. Vallet-Regí, M. Sebban, F. Taulelle, G. Férey, Angew. Chem. 118, 6120 (2006)

    Article  Google Scholar 

  25. A. Nikseresht, S. Ghasemi, S. Parak, Polyhedron 151, 112 (2018)

    Article  CAS  Google Scholar 

  26. J. Liu, L. Chen, H. Cui, J. Zhang, L. Zhang, C.-Y. Su, Chem. Soc. Rev. 43, 6011 (2014)

    Article  CAS  PubMed  Google Scholar 

  27. Y. Hu, L. Dai, D. Liu, W. Du, Y. Wang, Progress and prospect of metal-organic frameworks (MOFs) for enzyme immobilization (enzyme/MOFs). Renew. Sustain. Energy. Rev. 91, 793 (2018)

    Article  CAS  Google Scholar 

  28. J. Gordon, H. Kazemian, S. Rohani, Micropor. Mesopor. Mat. 162, 36 (2012)

    Article  CAS  Google Scholar 

  29. J.P. Tessonnier, S. Goubert-Renaudin, S. Alia, Y. Yan, M.A. Barteau, Langmuir 29, 393 (2013)

    Article  CAS  PubMed  Google Scholar 

  30. Q. Zhang, C. Yue, Q. Pu, T. Yang, Z. Wu, Y. Zhang, ACS Omega 4, 90419048 (2019)

    Google Scholar 

  31. M.J.D. Da Silva, N.A. Liberto, L.C.D.A. Leles, U.A. Pereira, J. Mol. Catal. A: Chem. 422, 69 (2016)

    Article  CAS  Google Scholar 

  32. S.W. Gong, L. Jing, H.H. Wang, L.J. Liu, Q. Zhang, Appl. Energy 134, 283 (2014)

    Article  CAS  Google Scholar 

  33. V.B. Veljković, J.M. Avramović, O.S. Stamenković, Renew. Sustain. Energy. Rev. 16, 1193 (2012)

    Article  CAS  Google Scholar 

  34. B. He, J.H. Van Gerpen, Biofuels 3, 479 (2012)

    Article  CAS  Google Scholar 

  35. N.N. Mahamuni, Y.G. Adewuyi, Energy. Fuels. 23, 2757 (2009)

    Article  CAS  Google Scholar 

  36. D. Boffito, F. Galli, C. Pirola, C. Bianchi, G. Patience, Ultrason. Sonochem. 21, 1969 (2014)

    Article  CAS  PubMed  Google Scholar 

  37. L.T. Thanh, K. Okitsu, Y. Sadanaga, N. Takenaka, Y. Maeda, H. Bandow, Bioresour. Technol. 101, 639 (2010)

    Article  CAS  Google Scholar 

  38. D.D. Pukale, G.L. Maddikeri, P.R. Gogate, A.B. Pandit, A.P. Pratap, Ultrason. Sonochem. 22, 278 (2015)

    Article  CAS  PubMed  Google Scholar 

  39. A.R. Gupta, S.V. Yadav, V.K. Rathod, Fuel 158, 800 (2015)

    Article  CAS  Google Scholar 

  40. A.K. Yadav, M.E. Khan, A. Pal, B. Singh, Biofuels 9(1), 101 (2018)

    Article  CAS  Google Scholar 

  41. R. Jogi, Y.S. Murthy, M. Satyanarayana, T.N. Rao, S. Javed, Energy. Sour. Part A. 38, 2610 (2016)

    Article  CAS  Google Scholar 

  42. P. Maneechakr, J. Samerjit, S. Karnjanakom, RSC. Adv. 5, 55252 (2015)

    Article  CAS  Google Scholar 

  43. S. Parida, D.K. Sahu, P.K. Misra, Energy. Sour. Part A. 38, 1110 (2016)

    Article  CAS  Google Scholar 

  44. E. Martinez-Guerra, V.G. Gude, Energy. Convers. Manage. 96, 268 (2015)

    Article  CAS  Google Scholar 

  45. E. Khosravi, A. Shariati, M.R.K. Nikou, Int. J. Oil. Gas. Coal. Technol. 11, 308 (2016)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors gratefully acknowledge Payame Noor University of Iran for financially supporting this research with the grant number of د/7/47416.

Author information

Authors and Affiliations

  1. Department of Chemistry, Ilam Branch, Islamic Azad University, Ilam, Iran

    Soraya Parak, Mohammad Alikarami & Saba Ghasemi

  2. Department of Chemistry, Payame Noor University (PNU), Tehran, 19395-4697, Iran

    Ahmad Nikseresht

Authors
  1. Soraya Parak
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ahmad Nikseresht
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mohammad Alikarami
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Saba Ghasemi
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

AN; did project administration, funding acquisition, supervision, review and editing. MA; done investigation; validation; and formal analysis. SP; was involved in investigation, writing—original draft preparation. SG; contributed to investigation, validation, formal analysis.

Corresponding authors

Correspondence to Ahmad Nikseresht or Mohammad Alikarami.

Ethics declarations

Conflict of interest

The authors have no relevant financial or non-financial interests to disclose. The authors have no competing interests to declare that are relevant to the content of this article. All authors certify that they have no affiliations with or involvement in any organization or entity with any financial interest or non-financial interest in the subject matter or materials discussed in this manuscript. The authors have no financial or proprietary interests in any material discussed in this article.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Parak, S., Nikseresht, A., Alikarami, M. et al. RSM optimization of biodiesel production by a novel composite of Fe(ΙΙΙ)-based MOF and phosphomolybdic acid. Res Chem Intermed 48, 3773–3793 (2022). https://doi.org/10.1007/s11164-022-04783-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-022-04783-w

Keywords

Search

Navigation