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Highly silver-selective fluorescent sensor based on functionalized nanoporous silica (SBA-Pr-NMP) in aqueous media

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Abstract

A new chemosensor based on silica entitled SBA-Pr-NMP was prepared by modification of SBA-15 with (3-aminopropyl)triethoxysilane and 3-methyl-1-phenyl-5-oxo-1H-pyrazole-4-carbaldehyde. The functionalized structure was characterized and confirmed via various methods like FT-IR, XRD, EDX, SEM, TGA, and BET. The sensing properties of SBA-Pr-NMP were studied using fluorescence spectroscopy in the presence of various metal ions, and the intensity increased remarkably with Ag+ ion compared to other cations. Also, a good linear relationship was obtained between the fluorescence intensity of SBA-Pr-NMP and the concentration of Ag+ with a calculated detection limit of 2.85 × 10–7 M.

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Acknowledgements

We gratefully acknowledge the Research Council of Alzahra University's support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, Tehran, Iran

    Negar Jamasbi, Ghodsi Mohammadi Ziarani & Fatemeh Mohajer

  2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Badiei

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  1. Negar Jamasbi
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  2. Ghodsi Mohammadi Ziarani
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  3. Fatemeh Mohajer
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  4. Alireza Badiei
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Correspondence to Negar Jamasbi or Ghodsi Mohammadi Ziarani.

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Jamasbi, N., Mohammadi Ziarani, G., Mohajer, F. et al. Highly silver-selective fluorescent sensor based on functionalized nanoporous silica (SBA-Pr-NMP) in aqueous media. Res Chem Intermed 48, 3957–3969 (2022). https://doi.org/10.1007/s11164-022-04773-y

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