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Catalytic oxidation of propylene on nano-copper oxide encapsulated in SAPO-34

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Abstract

Catalytic oxidation is one of the most effective methods for the removal of volatile organic compound. Nano-copper oxide encapsulated in SAPO-34 (CuO@SAPO-34) prepared by Trojan Horse method has been developed for the catalytic oxidation removal of propylene, which has been recognized as a highly polluted compound with high photochemical ozone creation potential. The effect of the activation treatment of CuO@SAPO-34 in different ambient gases on the catalytic activities for the oxidation of propylene has been investigated. XPS, TEM, Raman and O2-TPD measurements have been employed to investigate the local structure of nano-copper oxide encapsulated in SAPO-34. It was found that the activation treatment in nitrogen at high temperature plays a key role for the formation of copper superoxide species which leads to the catalytic oxidation of propylene into CO2 at low temperature, while the activation treatment in much more reductive gases led to the formation of Cu2O nanoparticles rather than Cu(II) superoxo species even after the same re-oxidation treatment.

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Acknowledgements

This work is supported by the National Key Research and Development Program of China (2017YFE0129000), Tianjin Municipal Science and Technology Bureau (18ZXSZSF00070, 18ZXSZSF00210), National Engineering Laboratory for Mobile Source Emission Control Technology (NELMS2018A14), the Fundamental Research Funds for the Central Universities and Nankai University (075-63201175, 075-92022027).

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Authors and Affiliations

  1. Department of Electronics and Tianjin Key Laboratory of Photo-Electronic Thin Film Device and Technology, Nankai University, Tianjin, 300350, People’s Republic of China

    Dongyue Qian, Chuntong Liu & Haijun Chen

  2. Emerging Industries Institute, Shanghai University, Jiaxing, 314006, Zhejiang, China

    Haijun Chen

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  1. Dongyue Qian
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  2. Chuntong Liu
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  3. Haijun Chen
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Correspondence to Haijun Chen.

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Qian, D., Liu, C. & Chen, H. Catalytic oxidation of propylene on nano-copper oxide encapsulated in SAPO-34. Res Chem Intermed 47, 183–193 (2021). https://doi.org/10.1007/s11164-020-04331-4

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