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BiCl3-modified perlite as an effective catalyst for selective organic transformations: a green protocol

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Abstract

A new perlite supported Bismuth Chloride (BiCl3) was used as an efficient heterogeneous catalyst for the synthesis of heterocyclic compounds viz., quinoxalines and dihydropyrimidinones. Fourier-transform infrared spectroscopy (FT–IR), scanning electron microscopy, energy dispersive spectra, X-ray diffractometry, thermogravimetric analysis and Brunauer–Emmett–Teller surface area analytical techniques were employed to characterize the prepared catalyst. Initially, the catalytic activity of the prepared BiCl3-Perlite was tested towards synthesis of simple quinoxaline derivatives at room temperature. The effect of solvent in the preparation of quinoxaline was also examined. The formed products were confirmed by their physical (melting point) and spectral data (FT–IR, 1H and 13C-NMR). In order to implement the activity of the BiCl3-Perlite catalyst, a multicomponent reaction was adopted for synthesis of dihydropyrimidinones under solvent free conditions in a micro oven. The use of recyclable heterogeneous solid acid catalyst makes the reaction simple with minimum chemical waste, shorter reaction time, easy workup and products in good yield.

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Acknowledgements

The authors are thankful to the management of the GRG Trust for providing financial support and necessary facilities. One of the authors, Balu Krishnakumar, is also thankful to FCT, for a post-doc grant (SFRH/BPD/86971/2012).

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Authors and Affiliations

  1. Department of Chemistry, PSGR Krishnammal College for Women, Coimbatore, 641004, India

    Kannan Brindha & Parasuraman Amutha

  2. Department of Chemistry, University of Coimbra, 3004-535, Coimbra, Portugal

    Balu Krishnakumar & Abílio José Fraga do Nascimento Sobral

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  1. Kannan Brindha
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Brindha, K., Amutha, P., Krishnakumar, B. et al. BiCl3-modified perlite as an effective catalyst for selective organic transformations: a green protocol. Res Chem Intermed 45, 4367–4381 (2019). https://doi.org/10.1007/s11164-019-03836-x

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