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Porphyrin dye/TiO2 entrenched in PET to attain self-cleaning property through visible light photocatalytic activity

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Abstract

A visible light sensitized hydrophilic self-cleaning poly ethylene terephthalate (PET) fabric exhibiting photocatalytic dye degrading properties has been prepared by step wise deposition of anatase TiO2, porphyrin with different anchor groups (TCPP, TCNPP, TPyP), the modified PET fabric showed excellent photo degradation of rhodamine dye. Moreover, the dye degradation ability in visible light irradiation for the modified fabric was also monitored at different time intervals by the UV–Vis spectral technique. The degradation efficiency was found to be in the order of PET/TiO2/TCPP > PET/TiO2/TCNPP > PET/TiO2/TPyP > TiO2 > PET. The surface modified PET was characterized by XPS, UV–Vis, and FESEM. Synthesized porphyrin and TiO2 were confirmed by 1H-NMR and XRD analysis, respectively.

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Acknowledgements

This study was supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (Grant No. NRF-2017R1E1A1A01074266). This work was supported by the industrial Fundamental Technology Development Program (10076350) funded by the Ministry of Trade, Industry and Energy (MOTIE) of Korea.

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Author notes

  1. Hyorim Kim and Ramalingam Manivannan contributed equally to this work.

Authors and Affiliations

  1. Department of Advanced Organic Materials Engineering, Chungnam National University, 220 Gung-dong, Yuseong-gu, Daejeon, 305-764, South Korea

    Hyorim Kim, Ramalingam Manivannan, Gisu Heo, Ji Won Ryu & Young-A Son

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  1. Hyorim Kim
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  2. Ramalingam Manivannan
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  3. Gisu Heo
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Correspondence to Young-A Son.

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Kim, H., Manivannan, R., Heo, G. et al. Porphyrin dye/TiO2 entrenched in PET to attain self-cleaning property through visible light photocatalytic activity. Res Chem Intermed 45, 3655–3671 (2019). https://doi.org/10.1007/s11164-019-03813-4

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