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Preparation and characterization of isatin complexed with Cu supported on 4-(aminomethyl) benzoic acid-functionalized Fe3O4 nanoparticles as a novel magnetic catalyst for the Ullmann coupling reaction

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Abstract

Isatin complexed with Cu supported on 4-(aminomethyl) benzoic acid-functionalized Fe3O4 nanoparticles (Cu-IS-AMBA-MNPs) as a new catalyst was designed, prepared and characterized by appropriate analyses. The heterogeneous reusable catalyst was successfully used for the efficient and widespread syntheses of diaryl ethers and diarylamines via the Ullmann coupling reaction. This green catalyst was easily removed, reused several times with no significant loss of its activity, and provided a clean synthesis with excellent yield and reduced time.

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Acknowledgement

We thank the Research Council of Razi University for generous financial support of this work.

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  1. Department of Organic Chemistry, Razi University, Kermanshah, 67149-67346, Iran

    Mohammad Mehdi Khodaei, Abdolhamid Alizadeh & Maryam Haghipour

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  1. Mohammad Mehdi Khodaei
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  3. Maryam Haghipour
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Correspondence to Mohammad Mehdi Khodaei.

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Khodaei, M.M., Alizadeh, A. & Haghipour, M. Preparation and characterization of isatin complexed with Cu supported on 4-(aminomethyl) benzoic acid-functionalized Fe3O4 nanoparticles as a novel magnetic catalyst for the Ullmann coupling reaction. Res Chem Intermed 45, 2727–2747 (2019). https://doi.org/10.1007/s11164-019-03760-0

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