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Magnetic nanoparticles functionalized ethane sulfonic acid (MNESA): as an efficient catalyst in the synthesis of coumarin derivatives using Pechmann condensation under mild condition

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Abstract

This paper reports an efficient heterogeneous catalyst based on sulfonic acid functionalization of magnetic nanoparticles. This new catalyst was prepared using the reaction between magnetic nanoparticles and sodium 2-bromoethane-1-sulfonate. Magnetic nanoparticles functionalized ethane sulfonic acid (MNESA) was found as efficient catalyst for the synthesis of coumarin derivatives using Pechmann condensation under mild condition. This reaction was catalyzed by MNESA under solvent-free condition at 90 °C, to give the corresponding products in excellent yields. The catalyst is easily separated from the reaction condition and can be reused for several times with consistence in the activity.

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Acknowledgments

We are thankful to Islamic Azad University central Tehran branch for partial support of this work.

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Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Central Tehran Branch, 19379-58814, Tehran, Iran

    Marjaneh Samadizadeh & Saeed Nouri

  2. Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, Mashhad, Iran

    Faeze Kiani Moghadam

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  1. Marjaneh Samadizadeh
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  2. Saeed Nouri
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  3. Faeze Kiani Moghadam
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Correspondence to Marjaneh Samadizadeh.

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Samadizadeh, M., Nouri, S. & Kiani Moghadam, F. Magnetic nanoparticles functionalized ethane sulfonic acid (MNESA): as an efficient catalyst in the synthesis of coumarin derivatives using Pechmann condensation under mild condition. Res Chem Intermed 42, 6089–6103 (2016). https://doi.org/10.1007/s11164-016-2447-5

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