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Synthesis and luminescence properties of novel carbazolyl-containing amino alcohol Schiff bases

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Abstract

Six novel carbazolyl-containing amino alcohol Schiff bases were synthesized by a solvent-free method, and characterized by 1H NMR, 13C NMR, mass, and infrared spectroscopy and elemental analysis. The conditions for synthesis by use of solvent and by this solvent-free method were investigated and optimized. The results showed the solvent-free method is better. The effect of the structure of the amino alcohol on the luminescence properties of the target Schiff bases was investigated. The results showed that 2-[(9-ethyl-9H-carbazol-3-ylmethylene)amino]-3-phenylpropan-1-ol had the best luminescence intensity; it has potential applications as a luminescent material in optics.

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Acknowledgments

The authors are grateful for the financial support of the National Natural Science Foundation of China (no. J1103312), the Natural Science Foundation of Hunan Province (no. 11JJ5005), the Innovative Research Team of the University (no. IRT1238), and the Science and Technology Project of Hunan Provincial Science and Technology Department (no. 2012GK3156). We also thank Dr William Hickey, the US Professor of HRM, for English editing of this paper.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People’s Republic of China

    Dong Li, Panliang Wu, Dongcai Guo, Yanru Yu, Haihua Xiao & Xi Jiang

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  1. Dong Li
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  2. Panliang Wu
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  3. Dongcai Guo
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  4. Yanru Yu
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  5. Haihua Xiao
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  6. Xi Jiang
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Correspondence to Dongcai Guo.

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Li, D., Wu, P., Guo, D. et al. Synthesis and luminescence properties of novel carbazolyl-containing amino alcohol Schiff bases. Res Chem Intermed 41, 2591–2601 (2015). https://doi.org/10.1007/s11164-013-1371-1

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  • DOI: https://doi.org/10.1007/s11164-013-1371-1

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