Skip to main content
SpringerLink
Log in

Elimination of the methyl blue from wastewater by advanced oxidation process in the presence of an heteropolyanion of Dawson type as a catalyst

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

This study involves the synthesis of a ferric compound called heteropolyanion of Dawson type (α 2P2W17FeO61)7−, which it is aimed to apply as a catalyst in an advanced oxidation process, in the presence of H2O2 to remove an organic pollutant, methyl blue (MB) located in the wastewater of textile industries. The study of the kinetics of the oxidation reaction was followed in aqueous solution in the presence of heteropolyanion (α 2P2W17FeO61)7−. To improve the kinetics of degradation of MB, different parameters controlling this reaction were varied. Among these parameters were the pH of the initial aqueous solution, the mass of the catalyst, the concentration of the oxidant (H2O2), the concentration of the dye, and temperature. The optimal conditions for a maximum rate conversion (100 %) are: pH 3, mass of the catalyst = 0.1 g, [H2O2]o = 0.4 mM, [M.B]o = 6 ppm, and temperature = 35 °C. The effects of salts present (chlorides and sulfates) in solution of dye was studied. The effects of the nature of the catalyst such as (α 2P2W18O62)6−; (α 2P2W17O61)10−; (α 2P2W17CoO61)8−; and (α 2P2W15Mo2FeO61)7− on the dye oxidation at room temperature were evaluated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14

Similar content being viewed by others

References

  1. J.M. Clemente-Juan, M. Clemente-León, E. Coronado, J.R. Galán-Mascarós, C. Giménez-Saiz, C.J. Gómez-García, C. R. Acad. Sci. Ser IIC Chem. 1, 305 (1998)

    Article  CAS  Google Scholar 

  2. N. Zabat, M. Abbessi, R. Kherrat, N. Jaffrezic-Renault, S. Zougar, A. Grid, Mater. Sci. Eng., C 28, 1006 (2008)

    Article  CAS  Google Scholar 

  3. N. Zabat, M. El H. Samar, M. Abbessi, Revue synthèse No. 21, (Université Badji Mokhtar, Annaba 2010)

  4. B. Keita, Y.W. Lu, L. Nadjo, R. Contant, M. Abbessi, J. Canny, M. Richet, J. Electroanal. Chem. 477, 146 (1999)

    Article  CAS  Google Scholar 

  5. B. keita, L. Nadjo, J. Mol. Catal. A: Chem. 262, 190 (2007)

    Article  CAS  Google Scholar 

  6. G.P. Romanelli, D.O. Bennardi, J.C. Autino, G.T. Baronetti, H.J. Thomas, E-J. Chem. 5, 641 (2008)

    Article  CAS  Google Scholar 

  7. M. Abbessi, R. Contant, R. Thouvenot, G. Hervé, Inorg. Chem. 30, 1695 (1991)

    Article  CAS  Google Scholar 

  8. J.P. Ciabrini, R. Contant, M. Fruchart, Polyhedron 2, 1229 (1983)

    Article  CAS  Google Scholar 

  9. R. Belghiche, R. Contant, Y.W. Lu, B. Keita, M. Abbessi, L. Nadjo, J. Mahuteau, Synthesis and caracterization of Fe-or Cu-substituted molybdenum-enriched tungstodiphosphates. Eur. J. Inorg. Chem. 6, 1410 (2002)

    Article  Google Scholar 

  10. B. Keita, F. Girard, L. Nadjo, R. Contant, R. Belghiche, M. Abbessi, J. Electroanal. 508, 70 (2001)

    Article  CAS  Google Scholar 

  11. B. Yue, Y. Zhou, J. Xu, Z. Wu, X. Zhang, Y. Zou, S. Jin, Environ. Sci. Technol. 36, 1325 (2002)

    Article  CAS  Google Scholar 

  12. J. Hu, R.C. Burns, J. Mol. Catal. A 184, 451 (2000)

    Article  Google Scholar 

  13. C. Allegre, M. Maisseub, F. Charbia, P. Moulina, J. Hazard. Mater. 116, 57 (2004)

    Article  CAS  Google Scholar 

  14. K.R. Ramakrishna, T. Viraraghavan, Water Sci. Technol. 36, 189 (1997)

    Article  CAS  Google Scholar 

  15. B. Ahling, K. Wiberger, J. Environ. Qual. 8, 12 (1979)

    Article  CAS  Google Scholar 

  16. S. Papic, N. Koprivanac, A.L.C. Bozic, Color. Technol. 116, 352 (2000)

    Article  CAS  Google Scholar 

  17. C.T. Benatti, C.R. Granhen Tavares, T.A. Guedes, J. Environ. Manage. 80, 66 (2006)

    Article  CAS  Google Scholar 

  18. F. Haber, J. Weiss, Proc. Roy. Soc. A 134, 332 (1934)

    Article  Google Scholar 

  19. F. Ji, C. Li, J. Zhang, L. Deng, Desalination 269, 284 (2001)

    Article  Google Scholar 

  20. Y. Zhang, C. He, J. Deng, Y. Tu, J. Liu, Y. Xiong, Res. Chem. Intermed. 35, 727 (2009)

    Article  CAS  Google Scholar 

  21. C. Wang, Y. Hua, Y. Tong, Electrochem. Acta 55, 6755 (2010)

    Article  CAS  Google Scholar 

  22. S.H. Tian, Y.T. Tu, D.S. Chen, X. Chen, Y. Xiong, Chem. Eng. J. 169, 31 (2001)

    Article  Google Scholar 

  23. C. Lee, D.L. Sedlak, J. Mol. Catal. A: Chem. 311, 1 (2009)

    Article  CAS  Google Scholar 

  24. M. Abbessi, Thèse de doctorat, Université de Paris, 1989

  25. B. Keita, E. Abdeldjalil, L. Nadjo, B. Avisse, R. Contant, J. Canny, M. Richet, Electrochem. Commun. 2, 145 (2000)

    Article  CAS  Google Scholar 

  26. C. Rocchiccioli-Deltcheff, R. Thouvenot, Spectrosc. Lett. 12, 127 (1979)

    Article  CAS  Google Scholar 

  27. H.A.A. Medien, S.M.E. Khalil, J. King Saud Univ. 22, 147 (2010)

    Article  Google Scholar 

  28. C.L. Hsueh, Y.H. Huang, C.C. Wang, C.Y. Chen, Chemosphere 58, 1409 (2005)

    Article  CAS  Google Scholar 

  29. H.-Y. Xu, X.-L. He, Z. Wu, L.-W. Shan, W.-D. Zhang, Bull. Korean Chem. Soc. 30, 2249 (2009)

    Article  CAS  Google Scholar 

  30. K. Ntampegliotis, A. Riga, V. Karayannisa, V. Bontozoglou, G. Papapolymerou, J. Hazard. Mater. 136, 75 (2006)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de recherche Génie de l’environnement, Département de Génie des Procédés, Faculté des sciences de l’ingéniorat, Université de Annaba, B.P. 12, 23000, Annaba, Algeria

    N. Zabat & M. Abbessi

Authors
  1. N. Zabat
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Abbessi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. Zabat.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zabat, N., Abbessi, M. Elimination of the methyl blue from wastewater by advanced oxidation process in the presence of an heteropolyanion of Dawson type as a catalyst. Res Chem Intermed 41, 1691–1702 (2015). https://doi.org/10.1007/s11164-013-1304-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-013-1304-z

Keywords

Search

Navigation