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Synthesis, spectral characterization, and luminescence properties of a cup-like ligand and its magnesium(II) complex

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Abstract

A new tripodal ligand, N,N′,N″-tri(salicylaldehyde)triaminotriethylamine (1) has been synthesized and characterized by elemental analysis, IR and UV spectroscopy, MS, and X-ray crystallography. X-ray diffraction analysis reveals that the three chains of the ligand form a cup-like structure. The ligand’s magnesium(II) complex has been synthesized and characterized by elemental analysis, conductivity, and IR and UV spectroscopy. The luminescence properties of the ligand and its magnesium(II) complex were investigated in DMF, CH3OH, and CH3CH2OH solution and in the solid state at room temperature.

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Acknowledgments

The authors would like to thank the National Natural Science Foundation of China (nos 21171132 and 20671073), the Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province (2010BSA07004), and the Science Foundation of Weifang University.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Weifang University, Weifang, 261061, China

    Xi-Shi Tai

  2. Department of Chemistry, Qinghai Normal University, Xining, 810008, China

    Wen-Hua Zhao

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  1. Xi-Shi Tai
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  2. Wen-Hua Zhao
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Correspondence to Xi-Shi Tai.

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Tai, XS., Zhao, WH. Synthesis, spectral characterization, and luminescence properties of a cup-like ligand and its magnesium(II) complex. Res Chem Intermed 40, 2075–2082 (2014). https://doi.org/10.1007/s11164-013-1103-6

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  • DOI: https://doi.org/10.1007/s11164-013-1103-6

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